900768
Berkessel-Katsuki epoxidation catalyst
≥98%
Manufacturer: Sigma Aldrich
CAS Number: 2055468-23-8
Synonym(S): Ti-Berkessel-Katsuki ligand complex, Titanium cis-1,2-diaminocyclohexane salalen catalyst
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 900768-100-MG | In Stock | ₹ 18,391.68 |
900768 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 18,391.68
GST (18%): ₹ 3,310.502
Total Price: ₹ 21,702.182
Quality Level
100
Assay
≥98%
form
powder or crystals
reaction suitability
core: titaniumreagent type: catalyst
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
Sigma Aldrich Fine Chemicals Biosciences Berkessel-Katsuki epoxidation catalyst >=98% | 2055468-23-8 | 100MG | -- | ₹ 22,786.67 |
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Description
- Application: Developed by Albrecht Berkessel′s lab, this is the first catalyst that allows catalytic enantioselective epoxidation of non-conjugated terminal double bonds with hydrogen peroxide as the oxidant. Eradicating multiple steps and kinetic resolution, this pre-formed chiral ligand-Ti2O2 catalyst complex provides a one-step route to enantiopure epoxides that are important intermediates for synthesis of bioactive compounds. Catalyst is recyclable under some conditions. For best results, pentafluorobenzoic acid P5360 or tetra-n-butylammonium hydrogensulfate 155837 is recommended as a co-catalyst.
- Other Notes: Titanium cis-1,2-Diaminocyclohexane Salalen Catalysts of Outstanding Activity and Enantioselectivity for the Asymmetric Epoxidation of Nonconjugated Terminal Olefins with Hydrogen Peroxide
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable