901235
TBS-DHG Catalyst
≥95%
Manufacturer: Sigma Aldrich
CAS Number: 212120-61-1
Synonym(S): (2R,3S,4R)-2-(((tert-Butyldimethylsilyl)oxy)methyl)tetrahydro-2H-pyran-3,4-diol, 6-Tertbutyldimethylsilyl-1,2-dihydroglucal
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 901235-100-MG | In Stock | ₹ 23,187.15 |
901235 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 23,187.15
GST (18%): ₹ 4,173.687
Total Price: ₹ 27,360.837
Quality Level
100
Assay
≥95%
form
powder or crystals
reaction suitability
reagent type: catalyst
greener alternative product characteristics
CatalysisLearn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
greener alternative category
, Aligned
storage temp.
−20°C
SMILES string
[H]C1([H])C([H])([H])O[C@@](C([H])([H])O[Si](C([H])([H])[H])(C([H])([H])[H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H])([H])[C@](O[H])([H])[C@]1([H])O[H]
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Description
- General description: We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
- Application: 6-Tertbutyldimethylsilyl-1,2-dihydroglucal (TBS-DHG) was reported by the Morken Lab to be an effective carbohydrate-derived catalyst for enantioselective diboration of alkenes. Related capabilities were observed with the dihydrorhamnal (DHR) catalyst (901237). TBS-DHG has also been used in ruthenium(0)catalyzed transfer hydrogenation cycloadditions.
- Other Notes: Carbohydrate-Catalyzed Enantioselective Alkene Diboration:Enhanced Reactivity of 1,2-Bonded Diboron ComplexesDiols, α-Ketols, and Diones as 22π Components in [2+2+2] Cycloadditions of 1,6-Diynes via Ruthenium(0)-Catalyzed Transfer HydrogenationCarbohydrate/DBU Cocatalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Quality Level: 100
Assay: ≥95%
form: powder or crystals
reaction suitability: reagent type: catalyst
greener alternative product characteristics: CatalysisLearn more about the Principles of Green Chemistry.
sustainability: Greener Alternative Product
greener alternative category: , Aligned
storage temp.: −20°C
SMILES string: [H]C1([H])C([H])([H])O[C@@](C([H])([H])O[Si](C([H])([H])[H])(C([H])([H])[H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H])([H])[C@](O[H])([H])[C@]1([H])O[H]
Quality Level:
100
Assay:
≥95%
form:
powder or crystals
reaction suitability:
reagent type: catalyst
greener alternative product characteristics:
CatalysisLearn more about the Principles of Green Chemistry.
sustainability:
Greener Alternative Product
greener alternative category:
, Aligned
storage temp.:
−20°C
SMILES string:
[H]C1([H])C([H])([H])O[C@@](C([H])([H])O[Si](C([H])([H])[H])(C([H])([H])[H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H])([H])[C@](O[H])([H])[C@]1([H])O[H]
Quality Level: 100
Assay: ≥97%
form: powder
reaction suitability: __
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100
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≥97%
form:
powder
reaction suitability:
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Quality Level: 100
Assay: ≥98%
form: powder or crystals
reaction suitability: __
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Quality Level:
100
Assay:
≥98%
form:
powder or crystals
reaction suitability:
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Quality Level: 100
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form: powder or crystals
reaction suitability: reaction type: C-C Bond Formationreagent type: catalystreagent type: ligandreaction type: C-H Activation
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100
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form:
powder or crystals
reaction suitability:
reaction type: C-C Bond Formationreagent type: catalystreagent type: ligandreaction type: C-H Activation
greener alternative product characteristics:
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