901166
cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride
Manufacturer: Sigma Aldrich
CAS Number: 1594113-05-9
Synonym(S): cis-((S)-BINAP)Ni(o-tolyl)Cl
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 901166-100-MG | In Stock | ₹ 11,312.13 |
901166 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 11,312.13
GST (18%): ₹ 2,036.183
Total Price: ₹ 13,348.313
form
powder or solid
Quality Level
100
reaction suitability
core: nickelreaction type: Cross Couplingsreagent type: catalyst
mp
>300 °C
SMILES string
Cl[Ni]1(P(C2=C([H])C([H])=C([H])C([H])=C2[H])(C3=C([H])C([H])=C([H])C([H])=C3[H])C(C([H])=C4[H])=[C@@]([C@@]5=C(P1(C6=C([H])C([H])=C([H])C([H])=C6[H])C7=C([H])C([H])=C([H])C([H])=C7[H])C([H])=C([H])C8=C5C([H])=C([H])C([H])=C8[H])C9=C4C([H])=C([H])C([H])=C
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | eMolecules AstaTech / CIS-((S)-BINAP)NI(O-TOLYL)CL / 0.1g / 746282927 / F73968 / 95.000 / 1594113-05-9 / [null] / 807.960 / C51H39ClNiP2 | eMolecules | ₹ 28,085.93 |
Related Products
Description
- Application: The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.
- Other Notes: Technology Spotlight: Jamison Nickel (II) PrecatalystsA Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes
- Legal Information: Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
Show Difference
form: powder or solid
Quality Level: 100
reaction suitability: core: nickelreaction type: Cross Couplingsreagent type: catalyst
mp: >300 °C
SMILES string: Cl[Ni]1(P(C2=C([H])C([H])=C([H])C([H])=C2[H])(C3=C([H])C([H])=C([H])C([H])=C3[H])C(C([H])=C4[H])=[C@@]([C@@]5=C(P1(C6=C([H])C([H])=C([H])C([H])=C6[H])C7=C([H])C([H])=C([H])C([H])=C7[H])C([H])=C([H])C8=C5C([H])=C([H])C([H])=C8[H])C9=C4C([H])=C([H])C([H])=C
form:
powder or solid
Quality Level:
100
reaction suitability:
core: nickelreaction type: Cross Couplingsreagent type: catalyst
mp:
>300 °C
SMILES string:
Cl[Ni]1(P(C2=C([H])C([H])=C([H])C([H])=C2[H])(C3=C([H])C([H])=C([H])C([H])=C3[H])C(C([H])=C4[H])=[C@@]([C@@]5=C(P1(C6=C([H])C([H])=C([H])C([H])=C6[H])C7=C([H])C([H])=C([H])C([H])=C7[H])C([H])=C([H])C8=C5C([H])=C([H])C([H])=C8[H])C9=C4C([H])=C([H])C([H])=C
form: solid
Quality Level: 100
reaction suitability: reagent type: catalystreaction type: Cross Couplings
mp: 160-173 °C (decomp)
SMILES string: CP(C(C)(C)C)C(C)(C)C.NC1=C(C2=C([Pd]OS(C)(=O)=O)C=CC=C2)C=CC=C1
form:
solid
Quality Level:
100
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
mp:
160-173 °C (decomp)
SMILES string:
CP(C(C)(C)C)C(C)(C)C.NC1=C(C2=C([Pd]OS(C)(=O)=O)C=CC=C2)C=CC=C1
form: solid
Quality Level: 100
reaction suitability: reagent type: catalystreaction type: Cross Couplings
mp: 163-169 °C (decomp.)
SMILES string: CC(C)(C)P(C(C)(C)C)C1=CC=CC=C1.NC2=C(C3=C([Pd]OS(C)(=O)=O)C=CC=C3)C=CC=C2
form:
solid
Quality Level:
100
reaction suitability:
reagent type: catalystreaction type: Cross Couplings
mp:
163-169 °C (decomp.)
SMILES string:
CC(C)(C)P(C(C)(C)C)C1=CC=CC=C1.NC2=C(C3=C([Pd]OS(C)(=O)=O)C=CC=C3)C=CC=C2
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