905259

Rh2(S-PTAD)4

Manufacturer: Sigma Aldrich

CAS Number: 909389-99-7

Synonym(S): Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)

Select a Size

Pack Size SKU Availability Price
50 MG 905259-50-MG In Stock ₹ 13,464.30
250 MG 905259-250-MG In Stock ₹ 52,281.00

905259 - 50 MG

₹ 13,464.30

In Stock

Quantity

1

Base Price: ₹ 13,464.30

GST (18%): ₹ 2,423.574

Total Price: ₹ 15,887.874

form

powder or crystals

mp

>300 °C

InChI

1S/4C20H21NO4.2Rh/c4*22-17-14-3-1-2-4-15(14)18(23)21(17)16(19(24)25)20-8-11-5-12(9-20)7-13(6-11)10-20;;/h4*1-4,11-13,16H,5-10H2,(H,24,25);;/q;;;;2*+2/p-4/t4*11-,12+,13-,16-,20?;;/m1111../s1

InChI key

SGEDWOHAUXKUGM-PAPHCAFZSA-J

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Description

  • Application: This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereocontrol.
  • Other Notes: Dirhodium Tetracarboxylate Derived from Adamantylglycine as a Chiral Catalyst for Carbenoid ReactionsDirhodium Tetracarboxylates Derived from Adamantylglycine as Chiral Catalysts for Enantioselective C-H AminationsEnantioselective Synthesis of Trifluoromethyl-?Substituted Cyclopropanes

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Show Difference

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Sigma Aldrich

905259

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form:
powder or crystals

mp:
>300 °C

InChI:
1S/4C20H21NO4.2Rh/c4*22-17-14-3-1-2-4-15(14)18(23)21(17)16(19(24)25)20-8-11-5-12(9-20)7-13(6-11)10-20;;/h4*1-4,11-13,16H,5-10H2,(H,24,25);;/q;;;;2*+2/p-4/t4*11-,12+,13-,16-,20?;;/m1111../s1

InChI key:
SGEDWOHAUXKUGM-PAPHCAFZSA-J

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90526

analytical standard...


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__

mp:
__

InChI:
1S/C18H26O4/c1-14(2)8-6-4-5-7-9-18(20)22-13-15-10-11-16(19)17(12-15)21-3/h6,8,10-12,14,19H,4-5,7,9,13H2,1-3H3/b8-6+

InChI key:
ZICNYIDDNJYKCP-SOFGYWHQSA-N

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solid

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InChI:
1S/C24H27BrP.BrH/c25-20-12-1-2-13-21-26(22-14-6-3-7-15-22,23-16-8-4-9-17-23)24-18-10-5-11-19-24;/h3-11,14-19H,1-2,12-13,20-21H2;1H/q+1;/p-1

InChI key:
RJXLPJGHUJHULP-UHFFFAOYSA-M

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form:
__

mp:
__

InChI:
__

InChI key:
__