905356

Rh2(R-PTAD)4

Manufacturer: Sigma Aldrich

CAS Number: 909393-65-3

Synonym(S): Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)

Select a Size

Pack Size SKU Availability Price
250 MG 905356-250-MG In Stock ₹ 52,281.00

905356 - 250 MG

₹ 52,281.00

In Stock

Quantity

1

Base Price: ₹ 52,281.00

GST (18%): ₹ 9,410.58

Total Price: ₹ 61,691.58

form

powder or crystals

mp

>300 °C

InChI

1S/4C20H21NO4.2Rh/c4*22-17-14-3-1-2-4-15(14)18(23)21(17)16(19(24)25)20-8-11-5-12(9-20)7-13(6-11)10-20;;/h4*1-4,11-13,16H,5-10H2,(H,24,25);;/q;;;;2*+2/p-4/t4*11-,12+,13-,16-,20?;;/m0000../s1

InChI key

SGEDWOHAUXKUGM-VMLWFVNWSA-J

Other Options

Image Product Name Manufacturer Price Range
AH87449
909393-65-3 | Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(R-PTAD)4
A2B Chem ₹ 42,095.52 - ₹ 1,21,666.32

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Description

  • Application: This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereo-control.
  • Other Notes: Dirhodium Tetracarboxylate Derived from Adamantylglycine as a Chiral Catalyst for Carbenoid ReactionsAsymmetric Synthesis of Tropanes by Rhodium-Catalyzed [4 + 3] CycloadditionAsymmetric [4 + 3] Cycloadditions between Vinylcarbenoids and Dienes: Application to the Total Synthesis of the Natural Product (−)-5-epi-Vibsanin E

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Sigma Aldrich

905356

--


form:
powder or crystals

mp:
>300 °C

InChI:
1S/4C20H21NO4.2Rh/c4*22-17-14-3-1-2-4-15(14)18(23)21(17)16(19(24)25)20-8-11-5-12(9-20)7-13(6-11)10-20;;/h4*1-4,11-13,16H,5-10H2,(H,24,25);;/q;;;;2*+2/p-4/t4*11-,12+,13-,16-,20?;;/m0000../s1

InChI key:
SGEDWOHAUXKUGM-VMLWFVNWSA-J

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