15230

[Bis(trifluoroacetoxy)iodo]benzene

purum, ≥95.0% (AT)

Manufacturer: Sigma Aldrich

CAS Number: 2712-78-9

Synonym(S): BTI, Iodobenzene I,I-bis(trifluoroacetate), PIFA

Select a Size

Pack Size SKU Availability Price
10 G 15230-10-G In Stock ₹ 5,466.63
50 G 15230-50-G In Stock ₹ 16,107.60

15230 - 10 G

₹ 5,466.63

In Stock

Quantity

1

Base Price: ₹ 5,466.63

GST (18%): ₹ 983.993

Total Price: ₹ 6,450.623

grade

purum

Quality Level

200

Assay

≥95.0% (AT)

form

solid

reaction suitability

reagent type: oxidant

mp

121-125 °C (lit.)122-125 °C

SMILES string

FC(F)(F)C(=O)O[I](OC(=O)C(F)(F)F)c1ccccc1

InChI

1S/C10H5F6IO4/c11-9(12,13)7(18)20-17(6-4-2-1-3-5-6)21-8(19)10(14,15)16/h1-5H

InChI key

PEZNEXFPRSOYPL-UHFFFAOYSA-N

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Description

  • Application: Reactant or reagent for:Pummerer-like reactionsChemoselective deprotection of dimethoxybenzyl ethersMediating oxidative cycloisomerizationTosyloxylation of anilides
  • Other Notes: Reagent for dehydrogenation and oxidation reactions, review[1]; New reagent for the direct conversions of amides to amines (Hofmann-type rearrangement) and key substance for carboxyterminal peptide sequencing[2]; Smooth dethioacetalization to the carbonyls[3]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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grade:
purum

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200

Assay:
≥95.0% (AT)

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solid

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mp:
121-125 °C (lit.)122-125 °C

SMILES string:
FC(F)(F)C(=O)O[I](OC(=O)C(F)(F)F)c1ccccc1

InChI:
1S/C10H5F6IO4/c11-9(12,13)7(18)20-17(6-4-2-1-3-5-6)21-8(19)10(14,15)16/h1-5H

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PEZNEXFPRSOYPL-UHFFFAOYSA-N

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DGIJAZGPLFOQJE-UHFFFAOYSA-N

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__

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InChI:
__

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__