274623
Dess-Martin periodinane
97%
Manufacturer: Sigma Aldrich
CAS Number: 87413-09-0
Synonym(S): 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 5 G | 274623-5-G | In Stock | ₹ 12,102.35 |
| 25 G | 274623-25-G | In Stock | ₹ 47,987.23 |
| 50 G | 274623-50-G | In Stock | ₹ 87,725.80 |
| 250 G | 274623-250-G | In Stock | ₹ 1,88,430.78 |
274623 - 5 G
In Stock
Quantity
1
Base Price: ₹ 12,102.35
GST (18%): ₹ 2,178.423
Total Price: ₹ 14,280.773
Quality Level
100
Assay
97%
reaction suitability
reagent type: oxidant
mp
130-133 °C (lit.)
storage temp.
−20°C
SMILES string
CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc12
InChI
1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChI key
NKLCNNUWBJBICK-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Chem-Impex International, Inc. 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one | 87413-09-0 | MFCD00130127 | 5G | Chem-Impex International, Inc. | ₹ 5,101.09 | |
 | Chem-Impex International, Inc. 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one | 87413-09-0 | MFCD00130127 | 100G | Chem-Impex International, Inc. | ₹ 39,752.89 | |
 | Chem-Impex International, Inc. 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one | 87413-09-0 | MFCD00130127 | 25G | Chem-Impex International, Inc. | ₹ 14,446.81 | |
 | Chemscene CS-0020511,AbaChemscene,Dess-Martin periodinane,87413-09-0,100g | Chemscene | -- | |
 | Dess-Martin periodinane solution | Sigma Aldrich | ₹ 3,863.70 - ₹ 19,139.63 | |
 | (1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one | Aaron Chemicals LLC | ₹ 342.24 - ₹ 19,251.00 | |
 | 87413-09-0 | Dess-martin periodinane | A2B Chem | ₹ 513.36 - ₹ 17,967.60 |
Related Products
Description
- General description: Dess-Martin periodinane (DMP) is a hypervalent iodine compound widely used as a mild reagent for the oxidation of primary/secondary alcohols to aldehydes/ketones; oxidation of amides into imides; the dehydrogenation of amines to nitriles, and disulfides to sulfones. It is also used to selectively oxidize alkenes to epoxides. This is a useful reaction for generating three-membered cyclic ethers. Additionally, DMP is used to oxidatively cleave 1,2-diols to form aldehydes or ketones and in the synthesis of lactones.
- Application: Dess–Martin periodinane is used as an oxidizing agent: For 1° and 2° alcohols to aldehydes and ketones. In the synthesis of N-protected α-amino aldehydes from the corresponding N-protected β-amino alcohols.[1] To synthesize alkynyl oxoaldehyde probe (AlkMGO). [2]
- Features and Benefits: Benefits of using DMP as an oxidizing reagent:milder reaction conditions (room temperature, neutral pH)shorter reaction times and higher yields high chemoselectivity tolerance of sensitive functional groups, and a long shelf lifesimplified workups
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P235 - P302 + P352 - P305 + P351 + P338 - P370 + P378 - P403 + P233
Hazard Classifications
Eye Irrit. 2 - Self-react. C - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
EUH044
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 97%
reaction suitability: reagent type: oxidant
mp: 130-133 °C (lit.)
storage temp.: −20°C
SMILES string: CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc12
InChI: 1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChI key: NKLCNNUWBJBICK-UHFFFAOYSA-N
Quality Level:
100
Assay:
97%
reaction suitability:
reagent type: oxidant
mp:
130-133 °C (lit.)
storage temp.:
−20°C
SMILES string:
CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc12
InChI:
1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChI key:
NKLCNNUWBJBICK-UHFFFAOYSA-N
Quality Level: 100
Assay: 95%
reaction suitability: __
mp: __
storage temp.: __
SMILES string: CC1C(C)C(=O)C(C)=C1C
InChI: 1S/C9H14O/c1-5-6(2)8(4)9(10)7(5)3/h5,7H,1-4H3
InChI key: ARUAYSANQMCCEN-UHFFFAOYSA-N
Quality Level:
100
Assay:
95%
reaction suitability:
__
mp:
__
storage temp.:
__
SMILES string:
CC1C(C)C(=O)C(C)=C1C
InChI:
1S/C9H14O/c1-5-6(2)8(4)9(10)7(5)3/h5,7H,1-4H3
InChI key:
ARUAYSANQMCCEN-UHFFFAOYSA-N
Quality Level: 100
Assay: ≥95.0% (GC)
reaction suitability: __
mp: __
storage temp.: __
SMILES string: CC(CC\C=C(\C)C)CC=O
InChI: 1S/C10H18O/c1-9(2)5-4-6-10(3)7-8-11/h5,8,10H,4,6-7H2,1-3H3
InChI key: NEHNMFOYXAPHSD-UHFFFAOYSA-N
Quality Level:
100
Assay:
≥95.0% (GC)
reaction suitability:
__
mp:
__
storage temp.:
__
SMILES string:
CC(CC\C=C(\C)C)CC=O
InChI:
1S/C10H18O/c1-9(2)5-4-6-10(3)7-8-11/h5,8,10H,4,6-7H2,1-3H3
InChI key:
NEHNMFOYXAPHSD-UHFFFAOYSA-N
Quality Level: __
Assay: __
reaction suitability: __
mp: __
storage temp.: __
SMILES string: __
InChI: __
InChI key: __
Quality Level:
__
Assay:
__
reaction suitability:
__
mp:
__
storage temp.:
__
SMILES string:
__
InChI:
__
InChI key:
__