186155

Lithium acetylide, ethylenediamine complex

90%

Manufacturer: Sigma Aldrich

CAS Number: 6867-30-7

Synonym(S): Lithium acetylide ethylenediamine complex, Lithium acetylide, compd. with 1,2-ethanediamine

Select a Size

Pack Size SKU Availability Price
10 G 186155-10-G In Stock ₹ 11,723.48
50 G 186155-50-G In Stock ₹ 19,712.33
100 G 186155-100-G In Stock ₹ 25,871.75

186155 - 10 G

₹ 11,723.48

In Stock

Quantity

1

Base Price: ₹ 11,723.48

GST (18%): ₹ 2,110.226

Total Price: ₹ 13,833.706

Quality Level

100

Assay

90%

bp

110.6 °C (lit.)

mp

76 °C (dec.)

storage temp.

2-8°C

SMILES string

[Li]C#C.NCCN

InChI

1S/C2H8N2.C2H.Li/c3-1-2-4;1-2;/h1-4H2;1H;

InChI key

QJQWXTYPTBEPGS-UHFFFAOYSA-N

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Description

  • Application: Lithium acetylide, ethylenediamine complex is a general reagent to synthesize ethynylated ketones.[1]It is used as a ligand in the coordination chemistry to synthesize transition metal complexes such as 1-alkynyl-dimethyl(triorganophosphine)gold(III) complex.[2]It is employed in the ring opening reaction of epoxides, as in the total synthesis of (−)-goniotrionin[3] and englerin A.[4]It can also be used in the ethynylation of alkyl halides to prepare terminal alkynes.[5]

SAFETY INFORMATION

Pictograms

GHS02,GHS05

Signal Word

Danger

Hazard Statements

H261,H314

Precautionary Statements

P231 + P232 - P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - Water-react 2

Supplementary Hazards

EUH014

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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bp:
110.6 °C (lit.)

mp:
76 °C (dec.)

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SMILES string:
[Li]C#C.NCCN

InChI:
1S/C2H8N2.C2H.Li/c3-1-2-4;1-2;/h1-4H2;1H;

InChI key:
QJQWXTYPTBEPGS-UHFFFAOYSA-N

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