189898

Methylmagnesium bromide solution

3.0 M in diethyl ether

Manufacturer: Sigma Aldrich

CAS Number: 75-16-1

Synonym(S): Bromomethylmagnesium

Select a Size

Pack Size SKU Availability Price
50 ML 189898-50-ML In Stock ₹ 9,082.18
100 ML 189898-100-ML In Stock ₹ 9,612.60
4 X 25 ML 189898-4-X-25-ML In Stock ₹ 17,081.85
4 X 100 ML 189898-4-X-100-ML In Stock ₹ 25,720.20
800 ML 189898-800-ML In Stock ₹ 36,079.73

189898 - 50 ML

₹ 9,082.18

In Stock

Quantity

1

Base Price: ₹ 9,082.18

GST (18%): ₹ 1,634.792

Total Price: ₹ 10,716.972

Quality Level

200

reaction suitability

reaction type: Grignard Reaction

concentration

3.0 M in diethyl ether

density

1.035 g/mL at 25 °C

SMILES string

C[Mg]Br

InChI

1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1

InChI key

AVFUHBJCUUTGCD-UHFFFAOYSA-M

Other Options

Image Product Name Manufacturer Price Range
282235
Methylmagnesium bromide solution
Sigma Aldrich ₹ 8,389.38 - ₹ 20,697.40
257087
Methylmagnesium bromide solution
Sigma Aldrich ₹ 22,526.83
302430
Methylmagnesium bromide solution
Sigma Aldrich ₹ 10,132.20
703583
Methylmagnesium bromide solution
Sigma Aldrich ₹ 13,931.78 - ₹ 49,697.58

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Description

  • General description: Methylmagnesium bromide solution, also known as bromomethylmagnesium, is both a Lewis acid and nucleophile. It is commonly used as a grignard reagent in organic synthesis reactions. [1]
  • Application: Methylmagnesium bromide solution (3M in diethyl ether) is used to synthesize:3S-(Boc-amino)-2,4-dimethyl-2-pentanol and methyl tert-butyl (S)-sulfoxide. [2] [3]Methyl potassium polyimide (K-PIM-1) (MeMgBr).[4] 3(4R)-{3(2R,3S)-[4′-(1′-triphenylmethyl)imidazole]-2-bromo-1-oxobutyl)-4-phenyl2-oxazolidinone[5]Benzyl 2-(2-oxopropyl)piperidine-1-carboxylate[6](R*, R*) 1-[1-(1-phenylethyl)pyrrolidin-2-yl]propan-2-one)[6]
  • Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
  • Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

SAFETY INFORMATION

Pictograms

GHS02,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H224,H260,H302,H314,H336

Precautionary Statements

P210 - P231 + P232 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P403 + P233

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system

Supplementary Hazards

EUH019

WGK

WGK 1

Flash Point(F)

-40.0 °F

Flash Point(C)

-40 °C

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189898

3.0 M in diethyl ether...


Quality Level:
200

reaction suitability:
reaction type: Grignard Reaction

concentration:
3.0 M in diethyl ether

density:
1.035 g/mL at 25 °C

SMILES string:
C[Mg]Br

InChI:
1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1

InChI key:
AVFUHBJCUUTGCD-UHFFFAOYSA-M

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density:
1.013 g/mL at 25 °C

SMILES string:
C[Mg]Cl

InChI:
1S/CH3.ClH.Mg/h1H3;1H;/q;;+1/p-1

InChI key:
RQNMYNYHBQQZSP-UHFFFAOYSA-M

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concentration:
__

density:
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SMILES string:
Cc1ccccc1C(O)c2ccccc2

InChI:
1S/C14H14O/c1-11-7-5-6-10-13(11)14(15)12-8-3-2-4-9-12/h2-10,14-15H,1H3

InChI key:
MXHXXJOHFRHBFB-UHFFFAOYSA-N

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__

concentration:
__

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1.03 g/mL at 25 °C (lit.)

SMILES string:
__

InChI:
__

InChI key:
__