189901

Methylmagnesium chloride solution

3.0 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 676-58-4

Synonym(S): Chloromethylmagnesium, Methyl magnesium chloride, Methylmagnesiumchloride

Select a Size

Pack Size SKU Availability Price
4 X 25 ML 189901-4-X-25-ML In Stock ₹ 7,913.08
100 ML 189901-100-ML In Stock ₹ 8,313.60
800 ML 189901-800-ML In Stock ₹ 31,511.58

189901 - 4 X 25 ML

₹ 7,913.08

In Stock

Quantity

1

Base Price: ₹ 7,913.08

GST (18%): ₹ 1,424.354

Total Price: ₹ 9,337.434

autoignition temp.

609 °F

Quality Level

200

reaction suitability

reaction type: Grignard Reaction

concentration

3.0 M in THF

density

1.013 g/mL at 25 °C

SMILES string

C[Mg]Cl

InChI

1S/CH3.ClH.Mg/h1H3;1H;/q;;+1/p-1

InChI key

RQNMYNYHBQQZSP-UHFFFAOYSA-M

Other Options

Image Product Name Manufacturer Price Range
50-186-0690
Sigma Aldrich Fine Chemicals Biosciences Methylmagnesium chloride solution 3.0 M in THF | 676-58-4 | MFCD00000468 | 8L
Sigma Aldrich Fine Chemicals Biosciences ₹ 1,44,373.94
50-165-7115
Sigma Aldrich Fine Chemicals Biosciences Methylmagnesium chloride solution 3.0M in THF, 676-58-4, MFCD00000468
Sigma Aldrich Fine Chemicals Biosciences ₹ 7,443.72
NC2011240
eMolecules​ 3M Methyl magnesium chloride in THF | 676-58-4 | | 25ml
eMolecules​ ₹ 2,941.55
50-186-0688
Sigma Aldrich Fine Chemicals Biosciences Methylmagnesium chloride solution 3.0 M in THF | 676-58-4 | MFCD00000468 | 4X25ML
Sigma Aldrich Fine Chemicals Biosciences ₹ 7,152.82
50-186-0689
Sigma Aldrich Fine Chemicals Biosciences Methylmagnesium chloride solution | 676-58-4 | MFCD00000468 | 800ml
Sigma Aldrich Fine Chemicals Biosciences ₹ 25,573.88
189901
Methylmagnesium chloride solution
Sigma Aldrich ₹ 7,913.08 - ₹ 31,511.58
AC85112
676-58-4 | Methylmagnesium Chloride
A2B Chem --

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Description

  • Application: Methylmagnesium chloride solution (3 M in THF) undergoes 1,3-addition with dialdose derived nitrones to form N-benzylhydroxylamines. The reductive cleavage of the N-O bond of these N-benzylhydroxylamines results in N-benzylaminosugars, which are key moieties of bioactive compounds. It can also react with Garner type aldehydes to form the corresponding secondary alcohols.[1]
  • Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
  • Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H260,H314,H335,H336,H351

Precautionary Statements

P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 1

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Show Difference

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Sigma Aldrich

189901

3.0 M in THF...


autoignition temp.:
609 °F

Quality Level:
200

reaction suitability:
reaction type: Grignard Reaction

concentration:
3.0 M in THF

density:
1.013 g/mL at 25 °C

SMILES string:
C[Mg]Cl

InChI:
1S/CH3.ClH.Mg/h1H3;1H;/q;;+1/p-1

InChI key:
RQNMYNYHBQQZSP-UHFFFAOYSA-M

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SMILES string:
Cc1ccccc1C(O)c2ccccc2

InChI:
1S/C14H14O/c1-11-7-5-6-10-13(11)14(15)12-8-3-2-4-9-12/h2-10,14-15H,1H3

InChI key:
MXHXXJOHFRHBFB-UHFFFAOYSA-N

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Sigma Aldrich

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__