227234

2-Mesitylmagnesium bromide solution

1.0 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 2633-66-1

Synonym(S): 2,4,6-Trimethylphenylmagnesium bromide

Select a Size

Pack Size SKU Availability Price
100 ML 227234-100-ML In Stock ₹ 16,432.35
800 ML 227234-800-ML In Stock ₹ 43,700.53

227234 - 100 ML

₹ 16,432.35

In Stock

Quantity

1

Base Price: ₹ 16,432.35

GST (18%): ₹ 2,957.823

Total Price: ₹ 19,390.173

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in THF

density

1.005 g/mL at 25 °C

SMILES string

Cc1cc(C)c([Mg]Br)c(C)c1

InChI

1S/C9H11.BrH.Mg/c1-7-4-8(2)6-9(3)5-7;;/h4-5H,1-3H3;1H;/q;;+1/p-1

InChI key

YXVSITSUDRGILL-UHFFFAOYSA-M

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Description

  • Application: 2-Mesitylmagnesium bromide is a Grignard reagent generally used to synthesize stable aromatic radical species such as dibenzoheptazethrene,[1] diindenoanthracene,[2] teranthene[3] and dimesitylindeno[2,1-a]fluorene[4] by kinetically blocking reactive molecular sites. It is also used in a variety of aromatic cross-coupling reactions.[5][6]

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H314,H335,H336,H351

Precautionary Statements

P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

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Sigma Aldrich

227234

1.0 M in THF...


Quality Level:
100

reaction suitability:
reaction type: Grignard Reaction

concentration:
1.0 M in THF

density:
1.005 g/mL at 25 °C

SMILES string:
Cc1cc(C)c([Mg]Br)c(C)c1

InChI:
1S/C9H11.BrH.Mg/c1-7-4-8(2)6-9(3)5-7;;/h4-5H,1-3H3;1H;/q;;+1/p-1

InChI key:
YXVSITSUDRGILL-UHFFFAOYSA-M

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100

reaction suitability:
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concentration:
__

density:
1.078 g/mL at 25 °C (lit.)

SMILES string:
O=C=NCc1ccccc1

InChI:
1S/C8H7NO/c10-7-9-6-8-4-2-1-3-5-8/h1-5H,6H2

InChI key:
YDNLNVZZTACNJX-UHFFFAOYSA-N

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Sigma Aldrich

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200

reaction suitability:
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concentration:
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density:
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SMILES string:
[Ag]OC(=O)c1ccccc1

InChI:
1S/C7H6O2.Ag/c8-7(9)6-4-2-1-3-5-6;/h1-5H,(H,8,9);/q;+1/p-1

InChI key:
CLDWGXZGFUNWKB-UHFFFAOYSA-M

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Sigma Aldrich

227285

powder...


Quality Level:
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reaction suitability:
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concentration:
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density:
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SMILES string:
Oc1cc(c2ccccc2c1[N+]#N)S([O-])(=O)=O

InChI:
1S/C10H6N2O4S/c11-12-10-7-4-2-1-3-6(7)9(5-8(10)13)17(14,15)16/h1-5H,(H-,13,14,15,16)

InChI key:
QHIBNGIZPPHJAT-UHFFFAOYSA-N