235253

(Diethylamino)sulfur trifluoride

95%

Manufacturer: Sigma Aldrich

CAS Number: 38078-09-0

Synonym(S): DAST, Diethylaminosulfur trifluoride

Select a Size

Pack Size SKU Availability Price
1 G 235253-1-G In Stock ₹ 2,533.05
5 G 235253-5-G In Stock ₹ 6,300.15
25 G 235253-25-G In Stock ₹ 20,805.65

235253 - 1 G

₹ 2,533.05

In Stock

Quantity

1

Base Price: ₹ 2,533.05

GST (18%): ₹ 455.949

Total Price: ₹ 2,988.999

Quality Level

100

Assay

95%

form

liquid

bp

30-32 °C/3 mmHg (lit.)

density

1.22 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CCN(CC)S(F)(F)F

InChI

1S/C4H10F3NS/c1-3-8(4-2)9(5,6)7/h3-4H2,1-2H3

InChI key

CSJLBAMHHLJAAS-UHFFFAOYSA-N

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Description

  • General description: Diethylamino sulfur trifluoride (DAST) is a fluorinating reagent used in the synthesis of fluorinated compounds and ring-opening reactions.[1]
  • Application: Fluorinating agent: reaction with alcohols and carbonyl compounds, Review[2][3]Review on nucleophilic fluorination.[3]Catalyst for Friedel-Crafts allylation using tertiary cyclopropyl silyl ethers[4] and the rearrangement of homoallylic alcohols to unsaturated aldehydes.[5]Early introduction of a fluoromethyl group stabilizes the epoxide during further manipulations in the synthesis of 26-fluoro-epothilone.[6]Fluorinating agent for a variety of compounds, including thioethers, alkenols, and cyanohydrins.[7][8][9]Reagent for gem difluorination of ketopipecolinic acids.[10]

SAFETY INFORMATION

Pictograms

GHS02,GHS05

Signal Word

Danger

Hazard Statements

H226,H242,H314

Precautionary Statements

P210 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378 - P403 + P235

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - Self-react. D - Skin Corr. 1A

Supplementary Hazards

EUH014

WGK

WGK 3

Flash Point(F)

73.4 °F

Flash Point(C)

23 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
100

Assay:
95%

form:
liquid

bp:
30-32 °C/3 mmHg (lit.)

density:
1.22 g/mL at 25 °C (lit.)

storage temp.:
2-8°C

SMILES string:
CCN(CC)S(F)(F)F

InChI:
1S/C4H10F3NS/c1-3-8(4-2)9(5,6)7/h3-4H2,1-2H3

InChI key:
CSJLBAMHHLJAAS-UHFFFAOYSA-N

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OCCSCCSCCO

InChI:
1S/C6H14O2S2/c7-1-3-9-5-6-10-4-2-8/h7-8H,1-6H2

InChI key:
PDHFSBXFZGYBIP-UHFFFAOYSA-N

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SMILES string:
Nc1ccccc1Cc2ccccc2

InChI:
1S/C13H13N/c14-13-9-5-4-8-12(13)10-11-6-2-1-3-7-11/h1-9H,10,14H2

InChI key:
DWOBGCPUQNFAFB-UHFFFAOYSA-N

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SMILES string:
CCCCOC

InChI:
1S/C5H12O/c1-3-4-5-6-2/h3-5H2,1-2H3

InChI key:
__