347116
Samarium(II) iodide solution
0.1 M in THF, contains samarium chips as stabilizer
Manufacturer: Sigma Aldrich
CAS Number: 32248-43-4
Synonym(S): Samarium diiodide
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 25 ML | 347116-25-ML | In Stock | ₹ 6,863.05 |
| 4 X 25 ML | 347116-4-X-25-ML | In Stock | ₹ 7,415.13 |
| 100 ML | 347116-100-ML | In Stock | ₹ 13,141.55 |
| 1 L | 347116-1-L | In Stock | ₹ 39,879.30 |
347116 - 25 ML
In Stock
Quantity
1
Base Price: ₹ 6,863.05
GST (18%): ₹ 1,235.349
Total Price: ₹ 8,098.399
form
liquid
Quality Level
200
contains
samarium chips as stabilizer
reaction suitability
core: samariumreagent type: catalystreaction type: Reductionsreagent type: reductant
concentration
0.1 M in THF
density
0.922 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
I[Sm]I
InChI
1S/2HI.Sm/h2*1H;/q;;+2/p-2
InChI key
UAWABSHMGXMCRK-UHFFFAOYSA-L
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Strem, An Ascensus Company CAS# 32248-43-4. 50ml. Samarium(II) iodide, 0.1M in THF. MFCD00058873 | Strem, An Ascensus Company | ₹ 5,159.27 | |
 | Samarium(II) iodide | Sigma Aldrich | ₹ 21,963.93 - ₹ 40,896.85 | |
| | Samarium(II) iodide | Sigma Aldrich | ₹ 21,963.93 - ₹ 40,896.85 | |
 | Samarium(II) iodide | Aaron Chemicals LLC | -- | |
 | 32248-43-4 | Samarium(II) iodide | A2B Chem | ₹ 44,576.76 |
Related Products
Description
- Application: Samarium(II) iodide solution (SmI2) can be used as a reagent in the synthesis of:Benzannulated pyrrolizidines and indolizidines by SmI2-induced cyclizations of indole derivatives.[1]Chiral 4-substituted 2-oxazolidinones and 5,5-disubstituted oxazolidinones through asymmetric Reformatsky type reaction.[2]γ-Aminoalkyl substituted γ-butyrolactones via ketyl-alkene coupling reaction.[3]It can also be used in:Reduction of conjugated double and triple bonds into alkenes using SmI2/H2O/amine mixtures.[4]Conversion of β-hydroxyketones into 1,3-diols by SmI2/H2O/Et3N.[5]Selective reduction of 6-membered lactones to the corresponding diols/triols using SmI2-H2O reagent system.[6]SmI2 is an effective single-electron reducing agent for the promotion of ketone-olefin, ketyl aryl cyclizations, and pinacol coupling reactions under mild conditions.[7][8][9] Often both intramolecular[10] and intermolecular[10] couplings proceed in a highly stereoselective fashion. It is also used in the synthesis of new heteroleptic samarium aryloxide/cyclopentadienide complexes.[11][12]
- Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
- Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P202 - P210 - P231 + P232 - P233 - P305 + P351 + P338 - P308 + P313
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3 - Water-react 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
EUH019
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
form: liquid
Quality Level: 200
contains: samarium chips as stabilizer
reaction suitability: core: samariumreagent type: catalystreaction type: Reductionsreagent type: reductant
concentration: 0.1 M in THF
density: 0.922 g/mL at 25 °C
storage temp.: 2-8°C
SMILES string: I[Sm]I
InChI: 1S/2HI.Sm/h2*1H;/q;;+2/p-2
InChI key: UAWABSHMGXMCRK-UHFFFAOYSA-L
form:
liquid
Quality Level:
200
contains:
samarium chips as stabilizer
reaction suitability:
core: samariumreagent type: catalystreaction type: Reductionsreagent type: reductant
concentration:
0.1 M in THF
density:
0.922 g/mL at 25 °C
storage temp.:
2-8°C
SMILES string:
I[Sm]I
InChI:
1S/2HI.Sm/h2*1H;/q;;+2/p-2
InChI key:
UAWABSHMGXMCRK-UHFFFAOYSA-L
form: liquid
Quality Level: __
contains: __
reaction suitability: __
concentration: __
density: 0.892 g/mL at 25 °C (lit.)
storage temp.: __
SMILES string: CC(C)C(=O)N(C)C
InChI: 1S/C6H13NO/c1-5(2)6(8)7(3)4/h5H,1-4H3
InChI key: GXMIHVHJTLPVKL-UHFFFAOYSA-N
form:
liquid
Quality Level:
__
contains:
__
reaction suitability:
__
concentration:
__
density:
0.892 g/mL at 25 °C (lit.)
storage temp.:
__
SMILES string:
CC(C)C(=O)N(C)C
InChI:
1S/C6H13NO/c1-5(2)6(8)7(3)4/h5H,1-4H3
InChI key:
GXMIHVHJTLPVKL-UHFFFAOYSA-N
form: __
Quality Level: 100
contains: __
reaction suitability: __
concentration: __
density: __
storage temp.: __
SMILES string: CCOC(=O)[C@@H](Br)CC[C@@H](Br)C(=O)OCC
InChI: 1S/C10H16Br2O4/c1-3-15-9(13)7(11)5-6-8(12)10(14)16-4-2/h7-8H,3-6H2,1-2H3/t7-,8+
InChI key: UBCNJHBDCUBIPB-OCAPTIKFSA-N
form:
__
Quality Level:
100
contains:
__
reaction suitability:
__
concentration:
__
density:
__
storage temp.:
__
SMILES string:
CCOC(=O)[C@@H](Br)CC[C@@H](Br)C(=O)OCC
InChI:
1S/C10H16Br2O4/c1-3-15-9(13)7(11)5-6-8(12)10(14)16-4-2/h7-8H,3-6H2,1-2H3/t7-,8+
InChI key:
UBCNJHBDCUBIPB-OCAPTIKFSA-N
form: liquid
Quality Level: 100
contains: __
reaction suitability: __
concentration: __
density: 1.017 g/mL at 25 °C (lit.)
storage temp.: __
SMILES string: CCOC(=O)C[C@@H](C)O
InChI: 1S/C6H12O3/c1-3-9-6(8)4-5(2)7/h5,7H,3-4H2,1-2H3/t5-/m1/s1
InChI key: __
form:
liquid
Quality Level:
100
contains:
__
reaction suitability:
__
concentration:
__
density:
1.017 g/mL at 25 °C (lit.)
storage temp.:
__
SMILES string:
CCOC(=O)C[C@@H](C)O
InChI:
1S/C6H12O3/c1-3-9-6(8)4-5(2)7/h5,7H,3-4H2,1-2H3/t5-/m1/s1
InChI key:
__