346160

Ethynylmagnesium chloride solution

0.5 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 65032-27-1

Synonym(S): Chloromagnesium acetylide

Select a Size

Pack Size SKU Availability Price
100 ML 346160-100-ML In Stock ₹ 6,787.28
800 ML 346160-800-ML In Stock ₹ 13,671.98

346160 - 100 ML

₹ 6,787.28

In Stock

Quantity

1

Base Price: ₹ 6,787.28

GST (18%): ₹ 1,221.71

Total Price: ₹ 8,008.99

form

liquid

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in THF

density

0.921 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Cl[Mg]C#C

InChI

1S/C2H.ClH.Mg/c1-2;;/h1H;1H;/q;;+1/p-1

InChI key

YEWNLGTVYUADOR-UHFFFAOYSA-M

Other Options

Image Product Name Manufacturer Price Range
AI01124
65032-27-1 | Magnesium,chloroethynyl- (9CI)
A2B Chem --

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Description

  • Application: Ethynylmagnesium chloride solution can be used:To synthesize 1-ethynyldeoxyribose derivatives which can further undergo Sonogashira coupling with various aryl, heteroaryl, and metallocenyl derivatives.[1]In one of the key synthetic steps of substituted naphthostyrils.[2]In the preparation of propargylic ester precursor for the synthesis of 1,3-dienylphosphonates.[3]

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS07

Signal Word

Danger

Hazard Statements

H225,H302,H319,H335,H336,H351

Precautionary Statements

P202 - P210 - P233 - P301 + P312 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

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form:
liquid

Quality Level:
100

reaction suitability:
reaction type: Grignard Reaction

concentration:
0.5 M in THF

density:
0.921 g/mL at 25 °C

storage temp.:
2-8°C

SMILES string:
Cl[Mg]C#C

InChI:
1S/C2H.ClH.Mg/c1-2;;/h1H;1H;/q;;+1/p-1

InChI key:
YEWNLGTVYUADOR-UHFFFAOYSA-M

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1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3

InChI key:
RXJKFRMDXUJTEX-UHFFFAOYSA-N

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