1-Propynylmagnesium bromide solution
0.5 M in THF
Manufacturer: Sigma Aldrich
CAS Number: 16466-97-0
Synonym(S): 1-Propyn-1-ylmagnesium bromide, Bromo(prop-1-yn-1-yl)magnesium, Bromo-1-propynylmagnesium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 ML | 429007-100-ML | In Stock | ₹ 14,910.00 |
| 800 ML | 429007-800-ML | In Stock | ₹ 40,270.00 |
429007 - 100 ML
In Stock
Quantity
1
Base Price: ₹ 14,910.00
GST (18%): ₹ 2,683.80
Total Price: ₹ 17,593.80
Quality Level
200
reaction suitability
reaction type: Grignard Reaction
concentration
0.5 M in THF
bp
65-67 °C
density
0.941 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
CC#C[Mg]Br
InChI
1S/C3H3.BrH.Mg/c1-3-2;;/h1H3;1H;/q;;+1/p-1
InChI key
YVJBCTFVENNIOV-UHFFFAOYSA-M
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences 1-Propynylmagnesium bromide solution 0.5 M in THF | 16466-97-0 | MFCD00216588 | 100ML | Sigma Aldrich Fine Chemicals Biosciences | ₹ 19,809.71 | |
 | Sigma Aldrich Fine Chemicals Biosciences 1-Propynylmagnesium bromide solution 0.5 M in THF | 16466-97-0 | MFCD00216588 | 800ML | Sigma Aldrich Fine Chemicals Biosciences | ₹ 44,456.98 | |
 | 16466-97-0 | Magnesium, bromo-1-propynyl- (8CI,9CI) | A2B Chem | -- |
Related Products
Description
- General description: 1-Propynylmagnesiumbromide solution is 1-propynylmagnesium bromide in 0.5M tetrahydrofuran.1-propynylmagnesium bromide solution used as a Grignard reagent in chemical synthesis. This research reagent can be used for chemical and organic transformations. It is used as a regent in the conversion of [11C]CO2 to [11C] amides via Mitsunobu reaction.[1][2]
- Application: Preparation of hydroxy enynes which underwent gold(I)-catalyzed benzannulation leading to tetrahydronaphthalenes.[3]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
EUH019
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 200
reaction suitability: reaction type: Grignard Reaction
concentration: 0.5 M in THF
bp: 65-67 °C
density: 0.941 g/mL at 25 °C
storage temp.: 2-8°C
SMILES string: CC#C[Mg]Br
InChI: 1S/C3H3.BrH.Mg/c1-3-2;;/h1H3;1H;/q;;+1/p-1
InChI key: YVJBCTFVENNIOV-UHFFFAOYSA-M
Quality Level: 100
reaction suitability: __
concentration: __
bp: __
density: __
storage temp.: __
SMILES string: Cl.NCCF
InChI: 1S/C2H6FN.ClH/c3-1-2-4;/h1-2,4H2;1H
InChI key: YRRZGBOZBIVMJT-UHFFFAOYSA-N
Quality Level: 200
reaction suitability: __
concentration: __
bp: 182 °C (lit.)
density: 1.093 g/mL at 25 °C (lit.)
storage temp.: 2-8°C
SMILES string: CC(C)(C)[Si](C)(C)OCCCBr
InChI: 1S/C9H21BrOSi/c1-9(2,3)12(4,5)11-8-6-7-10/h6-8H2,1-5H3
InChI key: __
