Isopropenylmagnesium bromide solution
0.5 M in THF
Manufacturer: Sigma Aldrich
CAS Number: 13291-18-4
Synonym(S): 1-Methylvinylmagnesium bromide, 1-Propen-2-ylmagnesium bromide, 2-Propen-2-ylmagnesium bromide, Bromo prop-1-en-2-yl magnesium, Bromo(isopropenylmagnesium), Isopropenylmagnesium bromide
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 ML | 419567-100-ML | In Stock | ₹ 18,489.10 |
| 800 ML | 419567-800-ML | In Stock | ₹ 47,521.75 |
419567 - 100 ML
In Stock
Quantity
1
Base Price: ₹ 18,489.10
GST (18%): ₹ 3,328.038
Total Price: ₹ 21,817.138
Quality Level
100
reaction suitability
reaction type: Grignard Reaction
concentration
0.5 M in THF
bp
67 °C
density
0.935 g/mL at 25 °C
SMILES string
CC(=C)[Mg]Br
InChI
1S/C3H5.BrH.Mg/c1-3-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChI key
LFTYALBVGVNGLI-UHFFFAOYSA-M
Other Options
Related Products
Description
- Application: Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat[1] and (S)-(−)-phosphonotrixin.[2] It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol.[3]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
EUH019
WGK
WGK 3
Flash Point(F)
35.6 °F
Flash Point(C)
2 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
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Quality Level: 100
reaction suitability: reaction type: Grignard Reaction
concentration: 0.5 M in THF
bp: 67 °C
density: 0.935 g/mL at 25 °C
SMILES string: CC(=C)[Mg]Br
InChI: 1S/C3H5.BrH.Mg/c1-3-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChI key: LFTYALBVGVNGLI-UHFFFAOYSA-M
Quality Level: 100
reaction suitability: reaction type: Grignard Reaction
concentration: 0.5 M in THF
bp: 65 °C
density: 0.937 g/mL at 25 °C
SMILES string: Br[Mg]CCC=C
InChI: 1S/C4H7.BrH.Mg/c1-3-4-2;;/h3H,1-2,4H2;1H;/q;;+1/p-1
InChI key: SMLLHQBZPPSOSR-UHFFFAOYSA-M
Quality Level: 100
reaction suitability: reaction type: Grignard Reaction
concentration: 0.5 M in THF
bp: 67 °C
density: 0.934 g/mL at 25 °C
SMILES string: C\C=C(/C)[Mg]Br
InChI: 1S/C4H7.BrH.Mg/c1-3-4-2;;/h3H,1-2H3;1H;/q;;+1/p-1
InChI key: FEJKWDUHNFCDRZ-UHFFFAOYSA-M
