526797
Cyclopropylmagnesium bromide solution
0.5 M in THF
Manufacturer: Sigma Aldrich
CAS Number: 23719-80-4
Synonym(S): Bromocyclopropylmagnesium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 ML | 526797-100-ML | In Stock | ₹ 46,428.43 |
| 800 ML | 526797-800-ML | In Stock | ₹ 1,69,855.08 |
526797 - 100 ML
In Stock
Quantity
1
Base Price: ₹ 46,428.43
GST (18%): ₹ 8,357.117
Total Price: ₹ 54,785.547
reaction suitability
reaction type: Grignard Reaction
Quality Level
100
concentration
0.5 M in THF
bp
65 °C
density
0.968 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Br[Mg]C1CC1
InChI
1S/C3H5.BrH.Mg/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1
InChI key
QUPLLJGAJVXXBW-UHFFFAOYSA-M
Other Options
Related Products
Description
- Application: Cyclopropylmagnesium bromide solution has been used in Grignard reaction that finds application as the key step in the preparation of aminopropylindenes, a chemotype of oxidosqualene cyclase (OSC) inhibitors from Grundmann′s ketone.[1] It can react with trimethylborate to form cyclopropylboronic acid, which can undergo Suzuki-type coupling reactions with different aryl, and heteroaryl bromides to form the cyclopropyl adducts.[2]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
EUH019
WGK
WGK 3
Flash Point(F)
1.0 °F
Flash Point(C)
-17.22 °C
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reaction suitability: reaction type: Grignard Reaction
Quality Level: 100
concentration: 0.5 M in THF
bp: 65 °C
density: 0.968 g/mL at 25 °C
storage temp.: 2-8°C
SMILES string: Br[Mg]C1CC1
InChI: 1S/C3H5.BrH.Mg/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1
InChI key: QUPLLJGAJVXXBW-UHFFFAOYSA-M
reaction suitability:
reaction type: Grignard Reaction
Quality Level:
100
concentration:
0.5 M in THF
bp:
65 °C
density:
0.968 g/mL at 25 °C
storage temp.:
2-8°C
SMILES string:
Br[Mg]C1CC1
InChI:
1S/C3H5.BrH.Mg/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1
InChI key:
QUPLLJGAJVXXBW-UHFFFAOYSA-M
reaction suitability: __
Quality Level: 100
concentration: __
bp: __
density: __
storage temp.: __
SMILES string: COc1cc(C=O)cc(F)c1O
InChI: 1S/C8H7FO3/c1-12-7-3-5(4-10)2-6(9)8(7)11/h2-4,11H,1H3
InChI key: OOGOFUKAJDPHDJ-UHFFFAOYSA-N
reaction suitability:
__
Quality Level:
100
concentration:
__
bp:
__
density:
__
storage temp.:
__
SMILES string:
COc1cc(C=O)cc(F)c1O
InChI:
1S/C8H7FO3/c1-12-7-3-5(4-10)2-6(9)8(7)11/h2-4,11H,1H3
InChI key:
OOGOFUKAJDPHDJ-UHFFFAOYSA-N
reaction suitability: __
Quality Level: 100
concentration: __
bp: __
density: __
storage temp.: __
SMILES string: __
InChI: __
InChI key: __
reaction suitability:
__
Quality Level:
100
concentration:
__
bp:
__
density:
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SMILES string:
__
InChI:
__
InChI key:
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reaction suitability: __
Quality Level: 100
concentration: __
bp: __
density: __
storage temp.: __
SMILES string: __
InChI: __
InChI key: __
reaction suitability:
__
Quality Level:
100
concentration:
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bp:
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density:
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storage temp.:
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SMILES string:
__
InChI:
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