420042

1-Methyl-2-propenylmagnesium chloride solution

0.5 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 21969-32-4

Select a Size

Pack Size SKU Availability Price
100 ML 420042-100-ML In Stock ₹ 7,956.38

420042 - 100 ML

₹ 7,956.38

In Stock

Quantity

1

Base Price: ₹ 7,956.38

GST (18%): ₹ 1,432.148

Total Price: ₹ 9,388.528

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in THF

bp

67 °C

density

0.917 g/mL at 25 °C

SMILES string

CC([Mg]Cl)C=C

InChI

1S/C4H7.ClH.Mg/c1-3-4-2;;/h3-4H,1H2,2H3;1H;/q;;+1/p-1

InChI key

RTJGBPYEBKZQGE-UHFFFAOYSA-M

Other Options

Image Product Name Manufacturer Price Range
50-176-2269
Sigma Aldrich Fine Chemicals Biosciences 1-Methyl-2-propenylmagnesium chloride solution 0.5 M in THF | 21969-32-4 | MFCD00216570 | 100ml
Sigma Aldrich Fine Chemicals Biosciences ₹ 38,989.69
AF64304
21969-32-4 | 1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE
A2B Chem --

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Description

  • Application: 1-Methyl-2-propenylmagnesium chloride is a Grignard type allylating reagent that can be used for the preparation of corresponding homoallylic alcohols by reacting with various aldehydes.[1] It can also be utilized in the synthesis of 3,4-dihydro-4-(1-methyl-2-propen-1-yl)-2(1H)-pyrimidinethione derivatives by treating with 2-mercaptopyrimidine.[2]

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H261,H302,H314,H335,H351

Precautionary Statements

P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2

Target Organs

Respiratory system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 3

Flash Point(F)

-4.0 °F

Flash Point(C)

-20 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
100

reaction suitability:
reaction type: Grignard Reaction

concentration:
0.5 M in THF

bp:
67 °C

density:
0.917 g/mL at 25 °C

SMILES string:
CC([Mg]Cl)C=C

InChI:
1S/C4H7.ClH.Mg/c1-3-4-2;;/h3-4H,1H2,2H3;1H;/q;;+1/p-1

InChI key:
RTJGBPYEBKZQGE-UHFFFAOYSA-M

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SMILES string:
COc1cc(COC(Cl)=O)c(cc1OC)[N+]([O-])=O

InChI:
1S/C10H10ClNO6/c1-16-8-3-6(5-18-10(11)13)7(12(14)15)4-9(8)17-2/h3-4H,5H2,1-2H3

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RWWPKIOWBQFXEE-UHFFFAOYSA-N

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reaction suitability:
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SMILES string:
[Cl-].COc1cc(ccc1O)-c2[o+]c3cc(O)cc(O)c3cc2O[C@@H]4O[C@H](CO)[C@@H](O)[C@H](O)[C@H]4O

InChI:
1S/C22H22O11.ClH/c1-30-15-4-9(2-3-12(15)25)21-16(7-11-13(26)5-10(24)6-14(11)31-21)32-22-20(29)19(28)18(27)17(8-23)33-22;/h2-7,17-20,22-23,27-29H,8H2,1H3,(H2-,24,25,26);1H/t17-,18-,19+,20-,22-;/m1./s1

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VDTNZDSOEFSAIZ-VXZFYHBOSA-N

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reaction suitability:
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SMILES string:
[K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O

InChI:
1S/2Cr.2K.7O/q;;2*+1;;;;;;2*-1

InChI key:
KMUONIBRACKNSN-UHFFFAOYSA-N