417149

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

97%

Manufacturer: Sigma Aldrich

CAS Number: 61676-62-8

Synonym(S): 4,4,5,5-Tetramethyl-2-[(propan-2-yl)oxy]-1,3,2-dioxaborolane, Isopropoxy 4,4,5,5-tetramethyl-1,3,2-dioxaborolane, Isopropoxyboronic acid pinacol ester, Isopropyl pinacol borate, Isopropylpinacolylborate

Select a Size

Pack Size SKU Availability Price
5 ML 417149-5-ML In Stock ₹ 2,349.03
25 ML 417149-25-ML In Stock ₹ 8,854.85
100 ML 417149-100-ML In Stock ₹ 20,394.30
500 ML 417149-500-ML In Stock ₹ 51,667.73

417149 - 5 ML

₹ 2,349.03

In Stock

Quantity

1

Base Price: ₹ 2,349.03

GST (18%): ₹ 422.825

Total Price: ₹ 2,771.855

Quality Level

100

Assay

97%

form

liquid

refractive index

n20/D 1.409 (lit.)

bp

73 °C/15 mmHg (lit.)

density

0.912 g/mL at 25 °C (lit.)

SMILES string

CC(C)OB1OC(C)(C)C(C)(C)O1

InChI

1S/C9H19BO3/c1-7(2)11-10-12-8(3,4)9(5,6)13-10/h7H,1-6H3

InChI key

MRWWWZLJWNIEEJ-UHFFFAOYSA-N

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Description

  • Application: 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane can be used as a reagent to borylate arenes[1][2] and to prepare fluorenylborolane.[3]It can also be used in the synthesis of following intermediates for generating conjugated copolymers:9,9-Dioctyl-2,7-bis(4,4,5,5-tetramethyl1,3,2-dioxaborolane-2-yl)dibenzosilole.[4]3,9-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5,11-di(1-decylundecyl)indolo[3,2-b]carbazole.[5]2,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-dioctylfluorene.[6]2,7-Bis(4′,4′,5′,5′-tetramethyl-1′,3′,2′-dioxaborolan-2′-yl)-N-9′′-heptadecanylcarbazole.[7]

SAFETY INFORMATION

Pictograms

GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H315,H319,H335

Precautionary Statements

P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Sigma Aldrich

417149

97%...


Quality Level:
100

Assay:
97%

form:
liquid

refractive index:
n20/D 1.409 (lit.)

bp:
73 °C/15 mmHg (lit.)

density:
0.912 g/mL at 25 °C (lit.)

SMILES string:
CC(C)OB1OC(C)(C)C(C)(C)O1

InChI:
1S/C9H19BO3/c1-7(2)11-10-12-8(3,4)9(5,6)13-10/h7H,1-6H3

InChI key:
MRWWWZLJWNIEEJ-UHFFFAOYSA-N

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41724

analytical standard...


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100

Assay:
≥97.0% (HPLC)

form:
__

refractive index:
__

bp:
__

density:
__

SMILES string:
[2H]c1c([2H])c(c([2H])c([2H])c1[N+]([O-])=O)C([2H])(O)C(CO)NC(=O)C(Cl)Cl

InChI:
1S/C11H12Cl2N2O5/c12-10(13)11(18)14-8(5-16)9(17)6-1-3-7(4-2-6)15(19)20/h1-4,8-10,16-17H,5H2,(H,14,18)/i1D,2D,3D,4D,9D

InChI key:
__

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Sigma Aldrich

417297

2.0 M in THF...


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Assay:
__

form:
liquid

refractive index:
__

bp:
67 °C

density:
1.033 g/mL at 25 °C

SMILES string:
C[Zn]Cl

InChI:
1S/CH3.ClH.Zn/h1H3;1H;/q;;+1/p-1

InChI key:
ASUSLKVOTPUROZ-UHFFFAOYSA-M

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Sigma Aldrich

417343

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Assay:
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form:
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refractive index:
__

bp:
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SMILES string:
OC1=CC(=O)Oc2ccc(Cl)cc12

InChI:
1S/C9H5ClO3/c10-5-1-2-8-6(3-5)7(11)4-9(12)13-8/h1-4,11H

InChI key:
HUMZENGQNOATEQ-UHFFFAOYSA-N