324647

Allylboronic acid pinacol ester

97%

Manufacturer: Sigma Aldrich

CAS Number: 72824-04-5

Synonym(S): 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane, 4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane, Allyl pinacol boronate, Pinacol allylboronate, Pinacolyl 2-propenylboronate

Select a Size

Pack Size SKU Availability Price
1 G 324647-1-G In Stock ₹ 4,394.95
10 G 324647-10-G In Stock ₹ 18,121.05

324647 - 1 G

₹ 4,394.95

In Stock

Quantity

1

Base Price: ₹ 4,394.95

GST (18%): ₹ 791.091

Total Price: ₹ 5,186.041

Quality Level

100

Assay

97%

refractive index

n20/D 1.4268 (lit.)

bp

50-53 °C/5 mmHg (lit.)

density

0.896 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC1(C)OB(CC=C)OC1(C)C

InChI

1S/C9H17BO2/c1-6-7-10-11-8(2,3)9(4,5)12-10/h6H,1,7H2,2-5H3

InChI key

YMHIEPNFCBNQQU-UHFFFAOYSA-N

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Description

  • General description: Allylboronic acid pinacol ester is used as a nucleophile in the catalytic allylation of simple ketoimines. [1]
  • Application: Reagent used forPalladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis[2] Intermolecular radical additions[3] Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids[4] Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes[5] Nucleic acid-templated energy transfer leading to a photorelease reaction[6] Stereoselective indium-catalyzed Hosomi-Sakurai reactions[7] Reagent used in Preparation ofCyclic sulfone hydroxyethylamines as BACE1 inhibitors for reduction of Amyloid β-Peptides[8] Transmetalation of carbene Ru iodide with Ag carboxylates to give C-H-activated Ru carbene complexes as catalysts for Z-selective olefin metathesis[9] Allylboronation reagent for the preparation of allylic alcohols[10], and homoallylic amines.[11]

SAFETY INFORMATION

Pictograms

GHS02

Signal Word

Warning

Hazard Statements

H226

Precautionary Statements

P210 - P233 - P240 - P241 - P242 - P243

Hazard Classifications

Flam. Liq. 3

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Sigma Aldrich

324647

97%...


Quality Level:
100

Assay:
97%

refractive index:
n20/D 1.4268 (lit.)

bp:
50-53 °C/5 mmHg (lit.)

density:
0.896 g/mL at 25 °C (lit.)

storage temp.:
2-8°C

SMILES string:
CC1(C)OB(CC=C)OC1(C)C

InChI:
1S/C9H17BO2/c1-6-7-10-11-8(2,3)9(4,5)12-10/h6H,1,7H2,2-5H3

InChI key:
YMHIEPNFCBNQQU-UHFFFAOYSA-N

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Fischer Scientific

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__

InChI:
__

InChI key:
__

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Fischer Scientific

3246490

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InChI:
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InChI key:
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2.0 M in diethyl ether...


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100

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__

bp:
__

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1.065 g/mL at 25 °C

storage temp.:
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SMILES string:
CC(C)(C)c1ccc([Mg]Br)cc1

InChI:
1S/C10H13.BrH.Mg/c1-10(2,3)9-7-5-4-6-8-9;;/h5-8H,1-3H3;1H;/q;;+1/p-1

InChI key:
YECFWFOEQLAVNH-UHFFFAOYSA-M