449563

Borane diphenylphosphine complex

98%

Manufacturer: Sigma Aldrich

CAS Number: 41593-58-2

Synonym(S): (Diphenylphosphine)trihydroboron

Select a Size

Pack Size SKU Availability Price
5 G 449563-5-G In Stock ₹ 26,520.00

449563 - 5 G

₹ 26,520.00

In Stock

Quantity

1

Base Price: ₹ 26,520.00

GST (18%): ₹ 4,773.60

Total Price: ₹ 31,293.60

Quality Level

100

Assay

98%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Reductionsreagent type: reductant

bp

148-150 °C/10 mmHg (lit.)

mp

47-50 °C (lit.)

SMILES string

B.[H]P(c1ccccc1)c2ccccc2

InChI

1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3

InChI key

XUFGOLYVDOBYLK-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-176-0856
Sigma Aldrich Fine Chemicals Biosciences Borane diphenylphosphine complex 98% | 41593-58-2 | MFCD00274254 | 5G
Sigma Aldrich Fine Chemicals Biosciences ₹ 33,958.76
AB71556
41593-58-2 | BORANE-DIPHENYLPHOSPHINE COMPLEX
A2B Chem ₹ 5,646.96 - ₹ 14,459.64

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Description

  • Application: Reactant for:Nucleophilic addition reactions (anion)Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxesDeprotonation reactionsCatalytic coupling with alkynyl bromidesCatalyst-free Staudinger ligation for indirect 18F-radiolabelingPreparation of chiral phosphine-phosphite bidentate ligands with biphenyl backboneReactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases

SAFETY INFORMATION

Pictograms

GHS02

Signal Word

Danger

Hazard Statements

H261

Precautionary Statements

P231 + P232 - P422

Hazard Classifications

Water-react 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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form:
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reaction suitability:
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligandreaction type: Reductionsreagent type: reductant

bp:
148-150 °C/10 mmHg (lit.)

mp:
47-50 °C (lit.)

SMILES string:
B.[H]P(c1ccccc1)c2ccccc2

InChI:
1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3

InChI key:
XUFGOLYVDOBYLK-UHFFFAOYSA-N

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