531634

Bis(pyridine)iodonium tetrafluoroborate

Manufacturer: Sigma Aldrich

CAS Number: 15656-28-7

Synonym(S): Barluenga reagent

Select a Size

Pack Size SKU Availability Price
1 G 531634-1-G In Stock ₹ 4,492.38

531634 - 1 G

₹ 4,492.38

In Stock

Quantity

1

Base Price: ₹ 4,492.38

GST (18%): ₹ 808.628

Total Price: ₹ 5,301.008

Quality Level

200

reaction suitability

reagent type: oxidant

mp

137-141 °C (lit.)

storage temp.

2-8°C

SMILES string

[I+].F[B-](F)(F)F.c1ccncc1.c2ccncc2

InChI

1S/2C5H5N.BF4.I/c2*1-2-4-6-5-3-1;2-1(3,4)5;/h2*1-5H;;/q;;-1;+1

InChI key

JBVUIHBKNVHCKK-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-511-476
Chem-Impex International, Inc. Bis(pyridine)iodonium tetrafluoroborate | 15656-28-7 | MFCD03703393 | 1G
Chem-Impex International, Inc. ₹ 5,261.94
AR001PHO
Iodine(1+), bis(pyridine)-, tetrafluoroborate(1-) (1:1)
Aaron Chemicals LLC ₹ 1,368.96 - ₹ 58,608.60
AA78592
15656-28-7 | Bis(pyridine)iodonium tetrafluoroborate
A2B Chem ₹ 1,711.20 - ₹ 31,828.32

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Description

  • General description: Bis(pyridine)iodonium Tetrafluoroborate (Barluenga′s reagent) is a mild iodinating[1] and oxidizing[2] reagent capable of selectively reacting with a wide range of unsaturated substrates and tolerates a variety of functional groups.
  • Application: Bis(pyridine)iodonium Tetrafluoroborate reacts with acetonides derived from simple terpenes to accomplish selective iodofunctionalization with excellent regio- and diastereofacial control.[3] It has been used as a reactant involved in:Synthesis of substituted naphthalenes[4] and oxygen containing heterocycles[5] from 2-alkynyl-substituted benzaldehydes.Synthesis of tetracyclic tetrahydrofurans[6]Applications for Bis(pyridine)iodonium Tetrafluoroborate

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Quality Level:
200

reaction suitability:
reagent type: oxidant

mp:
137-141 °C (lit.)

storage temp.:
2-8°C

SMILES string:
[I+].F[B-](F)(F)F.c1ccncc1.c2ccncc2

InChI:
1S/2C5H5N.BF4.I/c2*1-2-4-6-5-3-1;2-1(3,4)5;/h2*1-5H;;/q;;-1;+1

InChI key:
JBVUIHBKNVHCKK-UHFFFAOYSA-N

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CC(=O)Oc1cccc(C)c1

InChI:
1S/C9H10O2/c1-7-4-3-5-9(6-7)11-8(2)10/h3-6H,1-2H3

InChI key:
OTGAHJPFNKQGAE-UHFFFAOYSA-N