679585

4-Methoxybenzyl-2,2,2-trichloroacetimidate

Manufacturer: Sigma Aldrich

CAS Number: 89238-99-3

Synonym(S): p-Methoxybenzyl trichloroacetimidate

Select a Size

Pack Size SKU Availability Price
5 G 679585-5-G In Stock ₹ 9,147.13
25 G 679585-25-G In Stock ₹ 34,304.43

679585 - 5 G

₹ 9,147.13

In Stock

Quantity

1

Base Price: ₹ 9,147.13

GST (18%): ₹ 1,646.483

Total Price: ₹ 10,793.613

impurities

Major impurity is Trichloroacetamide by GCMS.

Quality Level

100

refractive index

n20/D 1.5488

bp

135-137 °C/0.7 mmHg

density

1.361 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

COc1ccc(COC(=N)C(Cl)(Cl)Cl)cc1

InChI

1S/C10H10Cl3NO2/c1-15-8-4-2-7(3-5-8)6-16-9(14)10(11,12)13/h2-5,14H,6H2,1H3

InChI key

TYHGKLBJBHACOI-UHFFFAOYSA-N

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Description

  • Application: 4-Methoxybenzyl-2,2,2-trichloroacetimidate can be used as a reagent for the protection of alcohols as the p-methoxybenzyl ether. 1o, 2o, and 3o alcohols can be easily protected using this reagent with equal efficiency in the presence of a variety of different protective groups. This reagent is commonly used under acidic conditions therefore it offers an alternative method to the Williamson ether synthesis, which is typically used basic conditions to protect base-sensitive alcohols.[1]

SAFETY INFORMATION

Pictograms

GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302 + H312 + H332,H315,H319,H335,H411

Precautionary Statements

P273 - P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

>230.0 °F

Flash Point(C)

> 110 °C

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Sigma Aldrich

679585

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impurities:
Major impurity is Trichloroacetamide by GCMS.

Quality Level:
100

refractive index:
n20/D 1.5488

bp:
135-137 °C/0.7 mmHg

density:
1.361 g/mL at 25 °C

storage temp.:
2-8°C

SMILES string:
COc1ccc(COC(=N)C(Cl)(Cl)Cl)cc1

InChI:
1S/C10H10Cl3NO2/c1-15-8-4-2-7(3-5-8)6-16-9(14)10(11,12)13/h2-5,14H,6H2,1H3

InChI key:
TYHGKLBJBHACOI-UHFFFAOYSA-N

Img

Supelco

67963

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impurities:
__

Quality Level:
100

refractive index:
__

bp:
__

density:
__

storage temp.:
__

SMILES string:
__

InChI:
1S/C7H8N2O/c1-9(8-10)7-5-3-2-4-6-7/h2-6H,1H3

InChI key:
MAXCWSIJKVASQC-UHFFFAOYSA-N

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Sigma Aldrich

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impurities:
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100

refractive index:
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bp:
__

density:
__

storage temp.:
__

SMILES string:
[H]C(=O)c1ccc(cc1)N(c2ccc(cc2)C([H])=O)c3ccc(cc3)C([H])=O

InChI:
1S/C21H15NO3/c23-13-16-1-7-19(8-2-16)22(20-9-3-17(14-24)4-10-20)21-11-5-18(15-25)6-12-21/h1-15H

InChI key:
YOXHQRNDWBRUOL-UHFFFAOYSA-N

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Sigma Aldrich

679674

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impurities:
__

Quality Level:
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refractive index:
__

bp:
__

density:
__

storage temp.:
2-8°C

SMILES string:
[O-]S(=O)(=O)C(F)(F)F.C[n+]1ccccc1OCc2ccccc2

InChI:
1S/C13H14NO.CHF3O3S/c1-14-10-6-5-9-13(14)15-11-12-7-3-2-4-8-12;2-1(3,4)8(5,6)7/h2-10H,11H2,1H3;(H,5,6,7)/q+1;/p-1

InChI key:
DUXHYQYOPHEFGC-UHFFFAOYSA-M