8.14815

Sodium chlorite

(25% solution in water) for synthesis

Manufacturer: Sigma Aldrich

Synonym(S): Chlorous acid, sodium salt

Select a Size

Pack Size SKU Availability Price
250 ML 8.14815-250-ML In Stock ₹ 4,540.01
1 L 8.14815-1-L In Stock ₹ 6,540.00

8.14815 - 250 ML

₹ 4,540.01

In Stock

Quantity

1

Base Price: ₹ 4,540.01

GST (18%): ₹ 817.202

Total Price: ₹ 5,357.212

vapor pressure

20 hPa ( 20 °C)

Quality Level

200

form

liquid

potency

1136 mg/kg LD50, oral (Rat)

pH

12-13 (20 °C in H2O)

bp

≥100 °C/1013 hPa

mp

<-3 °C

density

1.20-1.25 g/cm3 at 20 °C

storage temp.

2-30°C

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Description

  • Application: Sodium chlorite (NaClO2) can be used as an oxidizing agent for the conversion of: Aldehydes to corresponding carboxylic acids under mild reaction conditions in the presence of scavengers such as sulfamic acid or resorcinol.[1]Primary alcohols to carboxylic acids in the presence of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and NaOCl.[1] Aliphatic and aromatic thiols to the corresponding disulfides.[1]Aryl boronic acids to phenols via ipso-hydroxylation.[2]Cyclic benzylic ethers and N-protected cyclic benzylic amines to benzolactones and benzolactams.[3]Alkenes to epoxides using aldehydes as promoters.[4] Alkenes and cycloalkenes to 1, 2 diols via osmium-catalyzed Sharpless asymmetric dihydroxylation.[1] It can also be used in combination with Br2 to synthesize 2-carboxyazetidin-2-ones from furanylazetidinones.[1]
  • Analysis Note: Assay (iodometric): 23.0 - 26.0 %Density (d 20 °C/ 4 °C): 1.200 - 1.220

SAFETY INFORMATION

Pictograms

GHS05,GHS06,GHS08,GHS09

Signal Word

Danger

Hazard Statements

H290 - H302 - H311 - H314 - H373 - H400

Precautionary Statements

P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 - P314

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1 - STOT RE 2

Target Organs

spleen

Supplementary Hazards

EUH032

Storage Class Code

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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vapor pressure:
20 hPa ( 20 °C)

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200

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liquid

potency:
1136 mg/kg LD50, oral (Rat)

pH:
12-13 (20 °C in H2O)

bp:
≥100 °C/1013 hPa

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<-3 °C

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