345547
Hydrogen chloride solution
4.0 M in dioxane
Manufacturer: Sigma Aldrich
CAS Number: 7647-01-0
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 ML | 345547-100-ML | In Stock | ₹ 8,530.10 |
| 4 X 100 ML | 345547-4-X-100-ML | In Stock | ₹ 25,514.53 |
| 800 ML | 345547-800-ML | In Stock | ₹ 25,666.08 |
| 2 L | 345547-2-L | In Stock | ₹ 41,260.50 |
345547 - 100 ML
In Stock
Quantity
1
Base Price: ₹ 8,530.10
GST (18%): ₹ 1,535.418
Total Price: ₹ 10,065.518
form
liquid
Quality Level
200
concentration
3.80-4.40 M (by NaOH, titration)4.0 M in dioxane
density
1.05 g/mL at 25 °C
SMILES string
Cl
InChI
1S/ClH/h1H
InChI key
VEXZGXHMUGYJMC-UHFFFAOYSA-N
Other Options
...
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Description
- General description: Hydrogen chloride solution contains 4.0 M hydrogen chloride in 1,4-dioxane as the solvent. It is commonly used as a deprotection reagent during the deprotection of the tert-butoxycarbonyl (Boc) group of various amino acids and peptides. Additionally, it serves as a reagent in various organic synthesis reactions, including the synthesis of N-9-Fluorenylmethoxycarbonyl- (Fmoc) amino-acid chlorides. [1]
- Application: Hydrogen chloride solution (4.0 M in dioxane) can be used as: A reagent for the deprotection of the N-Boc protecting group from various heterocyclic derivatives.[2] A reagent for the deprotection of polymer protecting groups. For instance, deprotection of benzyl ether-protected polymer.[3] A polymerization initiator in combination with ZnCl2 in the synthesis of formyl terminated poly(ethyl vinyl ether) from ethyl vinyl ether (EVE).[4]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P202 - P210 - P233 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313
Hazard Classifications
Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
EUH019
WGK
WGK 3
Flash Point(F)
62.6 °F
Flash Point(C)
17 °C
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form: liquid
Quality Level: 200
concentration: 3.80-4.40 M (by NaOH, titration)4.0 M in dioxane
density: 1.05 g/mL at 25 °C
SMILES string: Cl
InChI: 1S/ClH/h1H
InChI key: VEXZGXHMUGYJMC-UHFFFAOYSA-N
form:
liquid
Quality Level:
200
concentration:
3.80-4.40 M (by NaOH, titration)4.0 M in dioxane
density:
1.05 g/mL at 25 °C
SMILES string:
Cl
InChI:
1S/ClH/h1H
InChI key:
VEXZGXHMUGYJMC-UHFFFAOYSA-N
form: crystals
Quality Level: 200
concentration: __
density: __
SMILES string: C1CNC2=NCCCN2C1
InChI: 1S/C7H13N3/c1-3-8-7-9-4-2-6-10(7)5-1/h1-6H2,(H,8,9)
InChI key: FVKFHMNJTHKMRX-UHFFFAOYSA-N
form:
crystals
Quality Level:
200
concentration:
__
density:
__
SMILES string:
C1CNC2=NCCCN2C1
InChI:
1S/C7H13N3/c1-3-8-7-9-4-2-6-10(7)5-1/h1-6H2,(H,8,9)
InChI key:
FVKFHMNJTHKMRX-UHFFFAOYSA-N
form: crystals
Quality Level: 200
concentration: __
density: __
SMILES string: C1CNC2=NCCCN2C1
InChI: 1S/C7H13N3/c1-3-8-7-9-4-2-6-10(7)5-1/h1-6H2,(H,8,9)
InChI key: FVKFHMNJTHKMRX-UHFFFAOYSA-N
form:
crystals
Quality Level:
200
concentration:
__
density:
__
SMILES string:
C1CNC2=NCCCN2C1
InChI:
1S/C7H13N3/c1-3-8-7-9-4-2-6-10(7)5-1/h1-6H2,(H,8,9)
InChI key:
FVKFHMNJTHKMRX-UHFFFAOYSA-N
form: solid
Quality Level: 100
concentration: __
density: __
SMILES string: CCCCCCCCCCCCCC(=O)CCCC(=O)OC
InChI: 1S/C19H36O3/c1-3-4-5-6-7-8-9-10-11-12-13-15-18(20)16-14-17-19(21)22-2/h3-17H2,1-2H3
InChI key: BVRPGVKJUHZXTH-UHFFFAOYSA-N
form:
solid
Quality Level:
100
concentration:
__
density:
__
SMILES string:
CCCCCCCCCCCCCC(=O)CCCC(=O)OC
InChI:
1S/C19H36O3/c1-3-4-5-6-7-8-9-10-11-12-13-15-18(20)16-14-17-19(21)22-2/h3-17H2,1-2H3
InChI key:
BVRPGVKJUHZXTH-UHFFFAOYSA-N