459674

Nickel(II) bromide 2-methoxyethyl ether complex

Manufacturer: Sigma Aldrich

CAS Number: 312696-09-6

Synonym(S): Diglyme nickel dibromide

Select a Size

Pack Size SKU Availability Price
5 G 459674-5-G In Stock ₹ 20,372.65

459674 - 5 G

₹ 20,372.65

In Stock

Quantity

1

Base Price: ₹ 20,372.65

GST (18%): ₹ 3,667.077

Total Price: ₹ 24,039.727

form

powder

Quality Level

100

reaction suitability

reagent type: catalystcore: nickel

SMILES string

Br[Ni]Br.COCCOCCOC

InChI

1S/C6H14O3.2BrH.Ni/c1-7-3-5-9-6-4-8-2;;;/h3-6H2,1-2H3;2*1H;/q;;;+2/p-2

InChI key

RRSIMIHTHWYRRA-UHFFFAOYSA-L

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Description

  • Application: Nickel(II) bromide 2-methoxyethyl ether complex can be used as a catalyst to prepare: Hindered diarylmethanols and benzylic alcohols by the addition of aryl halides to various aldehydes in the presence of Zn as a reducing agent.[1] Benzene-fused cyclic compounds via reductive dicarbofunctionalization of unactivated alkenes using less reactive benzyl chlorides.[2] Benzylboron derivatives via C-C cross-coupling reaction between substituted 5-bromo-3-methoxy-2-(trimethylsilyl)phenyl triflate and bromomethylboronic acid pinacol ester.[3] N-(Hetero)aryl sulfamides by N-arylation of sulfamides with aryl bromides in the presence of a photosensitizer.[4]

SAFETY INFORMATION

Pictograms

GHS02,GHS07

Signal Word

Danger

Hazard Statements

H228,H302 + H312 + H332,H315,H319,H335

Precautionary Statements

P210 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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form:
powder

Quality Level:
100

reaction suitability:
reagent type: catalystcore: nickel

SMILES string:
Br[Ni]Br.COCCOCCOC

InChI:
1S/C6H14O3.2BrH.Ni/c1-7-3-5-9-6-4-8-2;;;/h3-6H2,1-2H3;2*1H;/q;;;+2/p-2

InChI key:
RRSIMIHTHWYRRA-UHFFFAOYSA-L

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OCCCCOCc1ccccc1

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1S/C11H16O2/c12-8-4-5-9-13-10-11-6-2-1-3-7-11/h1-3,6-7,12H,4-5,8-10H2

InChI key:
TYROJDFHUXSBHC-UHFFFAOYSA-N

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