341622

Bromopentacarbonylmanganese(I)

98%

Manufacturer: Sigma Aldrich

CAS Number: 14516-54-2

Synonym(S): Bromopentacarbonylmanganese(I), Manganese pentacarbonyl bromide

Select a Size

Pack Size SKU Availability Price
5 G 341622-5-G In Stock ₹ 38,688.55

341622 - 5 G

₹ 38,688.55

In Stock

Quantity

1

Base Price: ₹ 38,688.55

GST (18%): ₹ 6,963.939

Total Price: ₹ 45,652.489

Quality Level

100

Assay

98%

form

powder or crystals

reaction suitability

core: manganesereagent type: catalyst

storage temp.

2-8°C

SMILES string

[Mn]Br.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1

InChI key

OESORJHGSXJTKX-UHFFFAOYSA-M

Other Options

Image Product Name Manufacturer Price Range
50-179-5686
Sigma Aldrich Fine Chemicals Biosciences Bromopentacarbonylmanganese(I) 98% | 14516-54-2 | MFCD00049806 | 5G
Sigma Aldrich Fine Chemicals Biosciences ₹ 31,652.92
50-204-5274
Strem, An Ascensus Company CAS# 14516-54-2. 1g. Manganese pentacarbonyl bromide, min. 98%. MFCD00049806
Strem, An Ascensus Company ₹ 8,521.78
50-901-10920
Strem, An Ascensus Company CAS# 14516-54-2. 5g. Manganese pentacarbonyl bromide, min. 98%. MFCD00049806
Strem, An Ascensus Company --
341622
Bromopentacarbonylmanganese(I)
Sigma Aldrich ₹ 38,688.55
AA73209
14516-54-2 | Bromopentacarbonylmanganese(I)
A2B Chem ₹ 2,909.04 - ₹ 52,961.64

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Description

  • Application: Bromopentacarbonylmanganese(I) can be used as:A precursor to synthesize manganese complex, [Mn(CO)5H], which was then used as a catalyst in the reduction of levulinic acid (LA) to methyltetrahydrofuran (MTHF) and the reductive amination of LA to N-substituted pyrrolidines.A precursor to prepare Mn(I) complexes bearing bifunctional ligands, which are used as catalysts for the transfer-hydrogenation of various ketones and imines using 2-propanol as the hydrogen donor.A catalyst in the selective C2-H activation reactions.

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302 + H312 + H332

Precautionary Statements

P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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SMILES string:
[Mn]Br.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI:
1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1

InChI key:
OESORJHGSXJTKX-UHFFFAOYSA-M

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c1ccncc1.CC(=N\O)\C(C)=N/O[Co](Cl)O\N=C(C)/C(C)=N\O

InChI:
1S/C5H5N.2C4H8N2O2.ClH.Co/c1-2-4-6-5-3-1;2*1-3(5-7)4(2)6-8;;/h1-5H;2*7-8H,1-2H3;1H;/q;;;;+3/p-3/b;2*5-3-,6-4-;;

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CKWAWSVVCRVWHW-PCJYWUFNSA-K

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[H][C@@]12C[C@H](C)[C@](O)(C(=O)CO)[C@@]1(C)C[C@H](O)[C@@]3(F)[C@@]2([H])CCC4=CC(=O)C=C[C@]34C

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