747769
[Ir(dtbbpy)(ppy)2]PF6
Manufacturer: Sigma Aldrich
CAS Number: 676525-77-2
Synonym(S): [Ir(dtbbpy)(ppy)2][PF6], Ir Photocatalyst, [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III) hexafluorophosphate
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 50 MG | 747769-50-MG | In Stock | ₹ 9,623.70 |
| 100 MG | 747769-100-MG | In Stock | ₹ 17,200.00 |
747769 - 50 MG
In Stock
Quantity
1
Base Price: ₹ 9,623.70
GST (18%): ₹ 1,732.266
Total Price: ₹ 11,355.966
form
powder
Quality Level
100
reaction suitability
core: iridiumreaction type: Photocatalysisreagent type: catalyst
photocatalyst activation
455 nm
storage temp.
2-8°C
SMILES string
CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F
InChI
1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;
InChI key
DZARMRZNOUWGQE-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | eMolecules (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) hexafluorophosphate | 676525-77-2 | MFCD27952560 | 1g | eMolecules | ₹ 24,559.14 | |
 | Sigma Aldrich Fine Chemicals Biosciences [Ir(dtbbpy)(ppy)2]PF6 | 676525-77-2 | MFCD27952560 | 50mg | Sigma Aldrich Fine Chemicals Biosciences | ₹ 11,634.45 | |
 | eMolecules [Ir(dtbbpy)(ppy)2]PF6 | 676525-77-2 | | 100mg | eMolecules | ₹ 12,090.48 | |
 | Chemscene AbaChemscene,[Ir(dtbbpy)(ppy)2]PF6,676525-77-2,Formula:C40H40F6IrN4P,M. Wt. 913.95,>98% | Chemscene | ₹ 3,642.29 | |
 | [Ir(dtbbpy)(ppy)2]PF6 | ChemScene | ₹ 1,454.52 - ₹ 3,22,475.64 |
Related Products
Description
- Application: [Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.[1]Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.[2]Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.[3]Aryl-alkyl C−C reductive cross-coupling reactions.[4]Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
Show Difference
form: powder
Quality Level: 100
reaction suitability: core: iridiumreaction type: Photocatalysisreagent type: catalyst
photocatalyst activation: 455 nm
storage temp.: 2-8°C
SMILES string: CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F
InChI: 1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;
InChI key: DZARMRZNOUWGQE-UHFFFAOYSA-N
form:
powder
Quality Level:
100
reaction suitability:
core: iridiumreaction type: Photocatalysisreagent type: catalyst
photocatalyst activation:
455 nm
storage temp.:
2-8°C
SMILES string:
CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F
InChI:
1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;
InChI key:
DZARMRZNOUWGQE-UHFFFAOYSA-N
form: solid
Quality Level: 100
reaction suitability: core: iridiumreagent type: catalystreaction type: Photocatalysis
photocatalyst activation: 450 nm
storage temp.: __
SMILES string: F[P](F)(F)(F)(F)F.CC(C)(C)C1=CC=[N@H]2C(=C1)C3=CC(=CC=[N@@H]3[Ir]2456c7cc(F)cc(F)c7C8=CC=C(C=[N]48)C(F)(F)F)C(C)(C)C.Fc9cc(F)c(C%10=[N]5C=C(C=C%10)C(F)(F)F)c6c9
InChI: __
InChI key: __
form:
solid
Quality Level:
100
reaction suitability:
core: iridiumreagent type: catalystreaction type: Photocatalysis
photocatalyst activation:
450 nm
storage temp.:
__
SMILES string:
F[P](F)(F)(F)(F)F.CC(C)(C)C1=CC=[N@H]2C(=C1)C3=CC(=CC=[N@@H]3[Ir]2456c7cc(F)cc(F)c7C8=CC=C(C=[N]48)C(F)(F)F)C(C)(C)C.Fc9cc(F)c(C%10=[N]5C=C(C=C%10)C(F)(F)F)c6c9
InChI:
__
InChI key:
__
form: solid
Quality Level: 100
reaction suitability: core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystreaction type: Cross Couplings
photocatalyst activation: __
storage temp.: __
SMILES string: NC1=CC=CC=C1C2=CC=CC=C2[Pd]Cl.P(C3CCCCC3)(C4=C(C5=CC=CC=C5)C=CC=C4)C6CCCCC6
InChI: 1S/C24H31P.C12H10N.ClH.Pd/c1-4-12-20(13-5-1)23-18-10-11-19-24(23)25(21-14-6-2-7-15-21)22-16-8-3-9-17-22;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h1,4-5,10-13,18-19,21-22H,2-3,6-9,14-17H2;1-6,8-9H,13H2;1H;/q;;;+1/p-1
InChI key: PLKOENXOQXWSIL-UHFFFAOYSA-M
form:
solid
Quality Level:
100
reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystreaction type: Cross Couplings
photocatalyst activation:
__
storage temp.:
__
SMILES string:
NC1=CC=CC=C1C2=CC=CC=C2[Pd]Cl.P(C3CCCCC3)(C4=C(C5=CC=CC=C5)C=CC=C4)C6CCCCC6
InChI:
1S/C24H31P.C12H10N.ClH.Pd/c1-4-12-20(13-5-1)23-18-10-11-19-24(23)25(21-14-6-2-7-15-21)22-16-8-3-9-17-22;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h1,4-5,10-13,18-19,21-22H,2-3,6-9,14-17H2;1-6,8-9H,13H2;1H;/q;;;+1/p-1
InChI key:
PLKOENXOQXWSIL-UHFFFAOYSA-M
form: solid
Quality Level: 100
reaction suitability: __
photocatalyst activation: __
storage temp.: __
SMILES string: __
InChI: __
InChI key: __
form:
solid
Quality Level:
100
reaction suitability:
__
photocatalyst activation:
__
storage temp.:
__
SMILES string:
__
InChI:
__
InChI key:
__