The Globally Harmonized System of Classification and Labeling of Chemicals (GHS) was introduced to ensure consistent, clear, and standardized hazard communication regarding chemicals globally. Developed by the United Nations, it aims to eliminate discrepancies in classification and labeling of hazardous chemicals across different countries and regions.
First established at the UN Conference on Environment and Development in Rio de Janeiro in 1992, GHS facilitates international trade and enhances safety through consistent and understandable classification of hazardous substances. The first formal version of the GHS was published in 2003, commonly referred to as the Purple Book, in contrast to the Orange Book used for transportation. The system is reviewed and updated regularly to adapt to new scientific knowledge and safety standards.
Description | Pictogram | Hazard Class and Hazard Category |
---|---|---|
Exploding Bomb | ![]() | Unstable explosives Explosives of division 1.1 to 1.4 Self-reactive substances, mixtures types A,B Organic peroxides, types A,B |
Flame | ![]() | Aerosols, cat. 1,2 Flammable solids, cat. 1,2 Flammable liquids, cat. 1,2,3 Flammable gases Flammable gas, cat. 1A,1B Pyrophoric gas, cat. 1A Chemically unstable gas, cat. 1A, 1B Self-reactive substances and mixtures, types B, C, D Chemicals under pressure, cat. 1,2 Pyrophoric liquids, cat. 1 Pyrophoric solids, cat. 1 Self-heating substances and mixtures, cat. 1,2 Substances and mixtures, which in contact with water, emit flammable gases, cat. 1,2,3 Self-reactive substances and mixtures, types E and F Organic peroxides type B,C,D,E,F Desensitized explosives, cat. 1,2,3,4 |
Flame Over Circle | ![]() | Oxidizing gases, cat. 1 Oxidizing liquids, cat. 1,2,3 Oxidizing solids, cat. 1,2,3 |
Gas Cylinder | ![]() | Chemicals under pressure, cat. 1,2,3 Gases under pressure Compressed gas Liquefied gas Refrigerated liquefied gas Dissolved gas |
Corrosion | ![]() | Corrosive to metals, cat. 1 Skin corrosion/irritation, cat. 1 (1A,1B,1C) Serious eye damage/eye irritation, cat. 1 |
Skull and Crossbones | ![]() | Acute toxicity, cat. 1,2,3 (Oral, Dermal, Inhalation) |
Exclamation Mark | ![]() | Acute toxicity, cat. 4 (Oral, Dermal, Inhalation) Skin corrosion/irritation, cat. 2 Serious eye damage/eye irritation, cat. 2/2A Skin sensitization, cat. 1,1A,1B Specific target organ toxicity, single exposure, cat. 3 Hazardous to the ozone layer, cat. 1 |
Health Hazard | ![]() | Respiratory sensitization, cat. 1, 1A, 1B Germ cell mutagenicity, cat. 1,1A,1B,2 Carcinogenicity, cat. 1,1A,1B,2 Reproductive toxicity, cat. 1,1A,1B,2 Specific target organ toxicity, single exposure, cat. 1,2 Specific target organ toxicity, repeated exposure, cat. 1,2 Aspiration hazard, cat. 1,2 |
Environment | ![]() | Hazardous to the aquatic environment, short-term (acute), cat. 1 Hazardous to the aquatic environment, long-term (chronic), cat. 1,2 |
Other Regional Elements (USA) | Simple Asphyxiant Combustible Dust Pyrophoric Gases |