364649
tert-Butylmagnesium chloride solution
1.0 M in THF
Manufacturer: Sigma Aldrich
CAS Number: 677-22-5
Synonym(S): t-Butylmagnesium chloride, tert-Butylchloromagnesium, Chloro(1,1-dimethylethyl)magnesium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 4 X 25 ML | 364649-4-X-25-ML | In Stock | ₹ 7,945.55 |
| 100 ML | 364649-100-ML | In Stock | ₹ 8,367.73 |
| 800 ML | 364649-800-ML | In Stock | ₹ 37,151.40 |
364649 - 4 X 25 ML
In Stock
Quantity
1
Base Price: ₹ 7,945.55
GST (18%): ₹ 1,430.199
Total Price: ₹ 9,375.749
Quality Level
200
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in THF
density
0.931 g/mL at 25 °C
SMILES string
CC(C)(C)[Mg]Cl
InChI
1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
InChI key
ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences tert-Butylmagnesium chloride solution | 677-22-5 | MFCD00000465 | 100mL | Sigma Aldrich Fine Chemicals Biosciences | ₹ 8,230.87 | |
| | Sigma Aldrich Fine Chemicals Biosciences tert-Butylmagnesium chloride solution | 677-22-5 | MFCD00000465 | 100mL | Sigma Aldrich Fine Chemicals Biosciences | ₹ 8,042.64 | |
 | Sigma Aldrich Fine Chemicals Biosciences tert-Butylmagnesium chloride solution 2.0 M in diethyl ether | 677-22-5 | MFCD00000465 | 800ML | Sigma Aldrich Fine Chemicals Biosciences | ₹ 39,304.55 | |
 | tert-Butylmagnesium chloride solution | Sigma Aldrich | ₹ 7,826.48 - ₹ 22,775.80 | |
| | tert-Butylmagnesium chloride solution | Sigma Aldrich | ₹ 7,945.55 - ₹ 37,151.40 | |
| | tert-Butylmagnesium chloride solution | Sigma Aldrich | ₹ 7,826.48 - ₹ 22,775.80 | |
 | 677-22-5 | tert-Butylmagnesium Chloride | A2B Chem | ₹ 6,074.76 |
Related Products
Description
- General description: tert-Butylmagnesium chloride, an organomagnesium compound, is commonly known as Grignard reagent. It is a powerful carbon nucleophile mainly used for C-C bond formation.[1]
- Application: tert-Butylmagnesium chloride (1.0 M in THF) has been used in the preparation of tert-butylsulfinyl chloride.[2] It can be used in: Grignard metathesis reaction of 2,5-dibromo-3-hexylthiophene to form 2-bromo-5-magnesiobromo-3-hexylthiophene.[3]A key step for the asymmetric synthesis of sulfinyl transfer agents using cinchona alkaloids quinine and quinidine as chiral auxiliaries.[4]
- Other Notes: Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and ocassional gentle swirling should redissolve the solid.
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
Target Organs
Respiratory system
Supplementary Hazards
EUH019
WGK
WGK 3
Flash Point(F)
1.4 °F
Flash Point(C)
-17 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 200
reaction suitability: reaction type: Grignard Reaction
concentration: 1.0 M in THF
density: 0.931 g/mL at 25 °C
SMILES string: CC(C)(C)[Mg]Cl
InChI: 1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
InChI key: ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Quality Level:
200
reaction suitability:
reaction type: Grignard Reaction
concentration:
1.0 M in THF
density:
0.931 g/mL at 25 °C
SMILES string:
CC(C)(C)[Mg]Cl
InChI:
1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
InChI key:
ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Quality Level: 100
reaction suitability: __
concentration: __
density: __
SMILES string: OC1=CC=C(NC(/C=C/C2=CC(O)=C(O)C=C2)=O)C(C(O)=O)=C1
InChI: 1S/C16H13NO6/c18-10-3-4-12(11(8-10)16(22)23)17-15(21)6-2-9-1-5-13(19)14(20)7-9/h1-8,18-20H,(H,17,21)(H,22,23)/b6-2+
InChI key: IDUUXROOZBOOPH-QHHAFSJGSA-N
Quality Level:
100
reaction suitability:
__
concentration:
__
density:
__
SMILES string:
OC1=CC=C(NC(/C=C/C2=CC(O)=C(O)C=C2)=O)C(C(O)=O)=C1
InChI:
1S/C16H13NO6/c18-10-3-4-12(11(8-10)16(22)23)17-15(21)6-2-9-1-5-13(19)14(20)7-9/h1-8,18-20H,(H,17,21)(H,22,23)/b6-2+
InChI key:
IDUUXROOZBOOPH-QHHAFSJGSA-N
Quality Level: 100
reaction suitability: reaction type: Grignard Reaction
concentration: 1.0 M in THF
density: 1.010 g/mL at 25 °C
SMILES string: CC[Mg]Br
InChI: 1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChI key: TWTWFMUQSOFTRN-UHFFFAOYSA-M
Quality Level:
100
reaction suitability:
reaction type: Grignard Reaction
concentration:
1.0 M in THF
density:
1.010 g/mL at 25 °C
SMILES string:
CC[Mg]Br
InChI:
1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChI key:
TWTWFMUQSOFTRN-UHFFFAOYSA-M
Quality Level: 100
reaction suitability: reaction type: Grignard Reaction
concentration: 1.0 M in THF
density: 1.010 g/mL at 25 °C
SMILES string: CC[Mg]Br
InChI: 1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChI key: TWTWFMUQSOFTRN-UHFFFAOYSA-M
Quality Level:
100
reaction suitability:
reaction type: Grignard Reaction
concentration:
1.0 M in THF
density:
1.010 g/mL at 25 °C
SMILES string:
CC[Mg]Br
InChI:
1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChI key:
TWTWFMUQSOFTRN-UHFFFAOYSA-M