479497

4,4′-(Phenylphosphinidene)bis(benzenesulfonic acid) dipotassium salt hydrate

97%

Manufacturer: Sigma Aldrich

CAS Number: 308103-66-4

Select a Size

Pack Size SKU Availability Price
1 G 479497-1-G In Stock ₹ 19,387.58
2.5 G 479497-2.5-G In Stock ₹ 44,393.33

479497 - 1 G

₹ 19,387.58

In Stock

Quantity

1

Base Price: ₹ 19,387.58

GST (18%): ₹ 3,489.764

Total Price: ₹ 22,877.344

Quality Level

100

Assay

97%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Coupling

mp

370 °C (dec.) (lit.)

functional group

phosphine

SMILES string

O.[K+].[K+].[O-]S(=O)(=O)c1ccc(cc1)P(c2ccccc2)c3ccc(cc3)S([O-])(=O)=O

InChI

1S/C18H15O6PS2.2K.H2O/c19-26(20,21)17-10-6-15(7-11-17)25(14-4-2-1-3-5-14)16-8-12-18(13-9-16)27(22,23)24;;;/h1-13H,(H,19,20,21)(H,22,23,24);;;1H2/q;2*+1;/p-2

InChI key

PRAGZPSLQQRHKD-UHFFFAOYSA-L

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SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Show Difference

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Sigma Aldrich

479497

97%...


Quality Level:
100

Assay:
97%

reaction suitability:
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Coupling

mp:
370 °C (dec.) (lit.)

functional group:
phosphine

SMILES string:
O.[K+].[K+].[O-]S(=O)(=O)c1ccc(cc1)P(c2ccccc2)c3ccc(cc3)S([O-])(=O)=O

InChI:
1S/C18H15O6PS2.2K.H2O/c19-26(20,21)17-10-6-15(7-11-17)25(14-4-2-1-3-5-14)16-8-12-18(13-9-16)27(22,23)24;;;/h1-13H,(H,19,20,21)(H,22,23,24);;;1H2/q;2*+1;/p-2

InChI key:
PRAGZPSLQQRHKD-UHFFFAOYSA-L

Img

Sigma Aldrich

479500

--


Quality Level:
100

Assay:
__

reaction suitability:
reagent type: ligandreaction type: Decarboxylationsreagent type: ligandreaction type: Negishi Couplingreagent type: ligandreaction type: Suzuki-Miyaura Coupling

mp:
92.5-96.5 °C (lit.)

functional group:
phosphine

SMILES string:
C1CCC(CC1)P(CCP(C2CCCCC2)C3CCCCC3)C4CCCCC4

InChI:
1S/C26H48P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h23-26H,1-22H2

InChI key:
BOUYBUIVMHNXQB-UHFFFAOYSA-N

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Sigma Aldrich

479519

in xylene, Pt ~2 %...


Quality Level:
200

Assay:
__

reaction suitability:
core: platinumreagent type: catalyst

mp:
12-13 °C

functional group:
__

SMILES string:
[Pt].C[Si](C)(O[Si](C)(C)C=C)C=C

InChI:
1S/C8H18OSi2.Pt/c1-7-10(3,4)9-11(5,6)8-2;/h7-8H,1-2H2,3-6H3;

InChI key:
__

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Quality Level:
100

Assay:
__

reaction suitability:
core: platinumreagent type: catalyst

mp:
__

functional group:
__

SMILES string:
[Pt].C[Si](C)(O[Si](C)(C)C=C)C=C

InChI:
1S/C8H18OSi2.Pt/c1-7-10(3,4)9-11(5,6)8-2;/h7-8H,1-2H2,3-6H3;

InChI key:
RCNRJBWHLARWRP-UHFFFAOYSA-N