662623

Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)]

95%

Manufacturer: Sigma Aldrich

CAS Number: 819050-89-0

Synonym(S): Rh2(esp)2

Select a Size

Pack Size SKU Availability Price
100 MG 662623-100-MG In Stock ₹ 8,990.00
500 MG 662623-500-MG In Stock ₹ 27,700.00

662623 - 100 MG

₹ 8,990.00

In Stock

Quantity

1

Base Price: ₹ 8,990.00

GST (18%): ₹ 1,618.20

Total Price: ₹ 10,608.20

Quality Level

100

Assay

95%

form

solid

reaction suitability

core: rhodiumreagent type: catalystreaction type: C-H Activation

mp

>300 °C

SMILES string

[Rh][Rh].CC(C)(Cc1cccc(CC(C)(C)C(O)=O)c1)C(O)=O.CC(C)(Cc2cccc(CC(C)(C)C(O)=O)c2)C(O)=O

InChI

1S/2C16H22O4.2Rh/c2*1-15(2,13(17)18)9-11-6-5-7-12(8-11)10-16(3,4)14(19)20;;/h2*5-8H,9-10H2,1-4H3,(H,17,18)(H,19,20);;

InChI key

OBMUTUNJWNQIAJ-UHFFFAOYSA-N

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Description

  • General description: Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionicacid)] has been identified as efficient C-H activation catalyst.
  • Application: Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Show Difference

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Sigma Aldrich

662623

95%...


Quality Level:
100

Assay:
95%

form:
solid

reaction suitability:
core: rhodiumreagent type: catalystreaction type: C-H Activation

mp:
>300 °C

SMILES string:
[Rh][Rh].CC(C)(Cc1cccc(CC(C)(C)C(O)=O)c1)C(O)=O.CC(C)(Cc2cccc(CC(C)(C)C(O)=O)c2)C(O)=O

InChI:
1S/2C16H22O4.2Rh/c2*1-15(2,13(17)18)9-11-6-5-7-12(8-11)10-16(3,4)14(19)20;;/h2*5-8H,9-10H2,1-4H3,(H,17,18)(H,19,20);;

InChI key:
OBMUTUNJWNQIAJ-UHFFFAOYSA-N

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SMILES string:
[Na+].[Na+].OC(=O)\C=C\C(O)=O.[O-]C(=O)\C=C\C([O-])=O.C=Cc1ccccc1

InChI:
1S/C8H8.C4H2O3/c1-2-8-6-4-3-5-7-8;5-3-1-2-4(6)7-3/h2-7H,1H2;1-2H

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WOLATMHLPFJRGC-UHFFFAOYSA-N

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Cc1ncccc1Br

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1S/C6H6BrN/c1-5-6(7)3-2-4-8-5/h2-4H,1H3

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AIPWPTPHMIYYOX-UHFFFAOYSA-N

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Cc1cc(Br)ccn1

InChI:
1S/C6H6BrN/c1-5-4-6(7)2-3-8-5/h2-4H,1H3

InChI key:
JFBMFWHEXBLFCR-UHFFFAOYSA-N