725455

Rhodium(II) triphenylacetate dimer

as complex with dichloromethane

Manufacturer: Sigma Aldrich

CAS Number: 142214-04-8

Synonym(S): Rh2(TPA)4, Rh2(triphenylacetate)4, Rhodiumtriphenylacetate, Tetrakis(triphenylacetato)dirhodium(II)

Select a Size

Pack Size SKU Availability Price
100 MG 725455-100-MG In Stock ₹ 10,700.40

725455 - 100 MG

₹ 10,700.40

In Stock

Quantity

1

Base Price: ₹ 10,700.40

GST (18%): ₹ 1,926.072

Total Price: ₹ 12,626.472

Quality Level

100

form

solid

reaction suitability

core: rhodiumreagent type: catalystreaction type: C-H Activation

mp

260-263 °C

SMILES string

ClCCl.O=C(O[Rh](OC(=O)C(c1ccccc1)(c2ccccc2)c3ccccc3)[Rh](OC(=O)C(c4ccccc4)(c5ccccc5)c6ccccc6)OC(=O)C(c7ccccc7)(c8ccccc8)c9ccccc9)C(c%10ccccc%10)(c%11ccccc%11)c%12ccccc%12

InChI

1S/4C20H16O2.CH2Cl2.2Rh/c4*21-19(22)20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;2-1-3;;/h4*1-15H,(H,21,22);1H2;;/q;;;;;2*+2/p-4

InChI key

SRAMLXDHXNCYQM-UHFFFAOYSA-J

Other Options

Image Product Name Manufacturer Price Range
50-174-0944
Sigma Aldrich Fine Chemicals Biosciences Rhodium(II) triphenylacetate dimer as complex with dichloromethane | 142214-04-8 | MFCD15071082 | 100MG
Sigma Aldrich Fine Chemicals Biosciences ₹ 14,149.91
CS-0081898
Rhodium(II) triphenylacetate dimer
ChemScene ₹ 4,192.44 - ₹ 49,967.04
AA69774
142214-04-8 | Tetrakis(triphenylacetato)dirhodium(ii) dichloromethane adduct
A2B Chem ₹ 1,368.96 - ₹ 49,967.04

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Description

  • Application: Catalyst for:Amination of allene carbamatesAllene aziridination to stereoselectively prepare cyclic cabamatesC-H bond nitrene insertionEnantioselective cyclopropanationPreparation of cyclic oxonium ylides

SAFETY INFORMATION

Pictograms

GHS08

Signal Word

Warning

Hazard Statements

H351

Precautionary Statements

P201 - P202 - P280 - P308 + P313 - P405 - P501

Hazard Classifications

Carc. 2

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Compare Similar Items

Show Difference

Img

Sigma Aldrich

725455

as complex with dichloromethane...


Quality Level:
100

form:
solid

reaction suitability:
core: rhodiumreagent type: catalystreaction type: C-H Activation

mp:
260-263 °C

SMILES string:
ClCCl.O=C(O[Rh](OC(=O)C(c1ccccc1)(c2ccccc2)c3ccccc3)[Rh](OC(=O)C(c4ccccc4)(c5ccccc5)c6ccccc6)OC(=O)C(c7ccccc7)(c8ccccc8)c9ccccc9)C(c%10ccccc%10)(c%11ccccc%11)c%12ccccc%12

InChI:
1S/4C20H16O2.CH2Cl2.2Rh/c4*21-19(22)20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;2-1-3;;/h4*1-15H,(H,21,22);1H2;;/q;;;;;2*+2/p-4

InChI key:
SRAMLXDHXNCYQM-UHFFFAOYSA-J

Img

Sigma Aldrich

725463

Umicore...


Quality Level:
100

form:
solid

reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp:
331 °C

SMILES string:
CC(C)c1cccc(C(C)C)c1N2C=CN(c3c(cccc3C(C)C)C(C)C)\C2=[Pd](\Cl)Cl.CC(C)c4cccc(C(C)C)c4N5C=CN(c6c(cccc6C(C)C)C(C)C)\C5=[Pd](\Cl)Cl

InChI:
1S/2C27H36N2.4ClH.2Pd/c2*1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;;;;;/h2*9-16,18-21H,1-8H3;4*1H;;/q;;;;;;2*+2/p-4

InChI key:
TXCXGICCIUAGJY-UHFFFAOYSA-J

Img

Sigma Aldrich

725471

packaged for use in deposition syst...


Quality Level:
__

form:
liquid

reaction suitability:
core: zirconium

mp:
__

SMILES string:
C[C]1[C][C][C][C]1.C[C]2[C][C][C][C]2.C[Zr]OC

InChI:
1S/2C6H7.CH3O.CH3.Zr/c2*1-6-4-2-3-5-6;1-2;;/h2*2-5H,1H3;1H3;1H3;/q;;-1;;+1

InChI key:
LFGIFPGCOXPKMG-UHFFFAOYSA-N

Img

Sigma Aldrich

725528

packaged for use in deposition syst...


Quality Level:
__

form:
liquid

reaction suitability:
core: zirconiumreagent type: catalyst

mp:
__

SMILES string:
CCN(C)[Zr](N(C)CC)(N(C)CC)N(C)CC

InChI:
1S/4C3H8N.Zr/c4*1-3-4-2;/h4*3H2,1-2H3;/q4*-1;+4

InChI key:
SRLSISLWUNZOOB-UHFFFAOYSA-N