667234
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
Manufacturer: Sigma Aldrich
CAS Number: 92390-26-6
Synonym(S): Cp*RuCl(cod), 1,5-Cyclooctadiene, ruthenium complex, Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium, Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 MG | 667234-250-MG | In Stock | ₹ 20,257.50 |
| 1 G | 667234-1-G | In Stock | ₹ 63,203.40 |
667234 - 250 MG
In Stock
Quantity
1
Base Price: ₹ 20,257.50
GST (18%): ₹ 3,646.35
Total Price: ₹ 23,903.85
reaction suitability
core: rutheniumreagent type: catalyst
Quality Level
100
mp
143-147 °C
storage temp.
−20°C
SMILES string
Cl[Ru].C1CC=CCCC=C1.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI
1S/C10H15.C8H12.ClH.Ru/c1-6-7(2)9(4)10(5)8(6)3;1-2-4-6-8-7-5-3-1;;/h1-5H3;1-2,7-8H,3-6H2;1H;/q;;;+1/p-1/b;2-1-,8-7-;;
InChI key
MQMQNIQJGNBEMG-ONEVTFJLSA-M
Other Options
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Description
- Application: Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.[1]It can be used: To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.[2]To catalyze C-C coupling of norbornenes and norbornadiene with alkynes to form [2 + 2] cycloadducts.[3]In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.[4]To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.[5]To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.[6]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Water-react 2
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves