667234
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
Manufacturer: Sigma Aldrich
CAS Number: 92390-26-6
Synonym(S): Cp*RuCl(cod), 1,5-Cyclooctadiene, ruthenium complex, Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium, Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 MG | 667234-250-MG | In Stock | ₹ 20,257.50 |
| 1 G | 667234-1-G | In Stock | ₹ 63,203.40 |
667234 - 250 MG
In Stock
Quantity
1
Base Price: ₹ 20,257.50
GST (18%): ₹ 3,646.35
Total Price: ₹ 23,903.85
reaction suitability
core: rutheniumreagent type: catalyst
Quality Level
100
mp
143-147 °C
storage temp.
−20°C
SMILES string
Cl[Ru].C1CC=CCCC=C1.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI
1S/C10H15.C8H12.ClH.Ru/c1-6-7(2)9(4)10(5)8(6)3;1-2-4-6-8-7-5-3-1;;/h1-5H3;1-2,7-8H,3-6H2;1H;/q;;;+1/p-1/b;2-1-,8-7-;;
InChI key
MQMQNIQJGNBEMG-ONEVTFJLSA-M
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) | 92390-26-6 | MFCD07369035 | 1G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 37,837.20 | |
 | Strem, An Ascensus Company CAS# 92390-26-6. 250mg. Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II), 98%. MFCD07369035 | Strem, An Ascensus Company | ₹ 12,628.66 | |
 | Sigma Aldrich Fine Chemicals Biosciences Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) | 92390-26-6 | MFCD07369035 | 250MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 14,149.91 | |
 | Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II) | Aaron Chemicals LLC | ₹ 342.24 - ₹ 50,822.64 |
Related Products
Description
- Application: Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.[1]It can be used: To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.[2]To catalyze C-C coupling of norbornenes and norbornadiene with alkynes to form [2 + 2] cycloadducts.[3]In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.[4]To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.[5]To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.[6]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Water-react 2
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Show Difference
reaction suitability: core: rutheniumreagent type: catalyst
Quality Level: 100
mp: 143-147 °C
storage temp.: −20°C
SMILES string: Cl[Ru].C1CC=CCCC=C1.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI: 1S/C10H15.C8H12.ClH.Ru/c1-6-7(2)9(4)10(5)8(6)3;1-2-4-6-8-7-5-3-1;;/h1-5H3;1-2,7-8H,3-6H2;1H;/q;;;+1/p-1/b;2-1-,8-7-;;
InChI key: MQMQNIQJGNBEMG-ONEVTFJLSA-M
reaction suitability:
core: rutheniumreagent type: catalyst
Quality Level:
100
mp:
143-147 °C
storage temp.:
−20°C
SMILES string:
Cl[Ru].C1CC=CCCC=C1.C[C]2[C](C)[C](C)[C](C)[C]2C
InChI:
1S/C10H15.C8H12.ClH.Ru/c1-6-7(2)9(4)10(5)8(6)3;1-2-4-6-8-7-5-3-1;;/h1-5H3;1-2,7-8H,3-6H2;1H;/q;;;+1/p-1/b;2-1-,8-7-;;
InChI key:
MQMQNIQJGNBEMG-ONEVTFJLSA-M
reaction suitability: core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst
Quality Level: 100
mp: 176.7-187.1 °C
storage temp.: __
SMILES string: C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.CC(C)(C)c4ccc(OP(Oc5ccc(cc5C(C)(C)C)C(C)(C)C)Oc6c([Pd]Cl)cc(cc6C(C)(C)C)C(C)(C)C)c(c4)C(C)(C)C
InChI: 1S/C42H62O3P.C18H33P.ClH.Pd/c1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h19-23,25-27H,1-18H3;16-18H,1-15H2;1H;/q;;;+1/p-1
InChI key: KSWCAUMOXBNXFL-UHFFFAOYSA-M
reaction suitability:
core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst
Quality Level:
100
mp:
176.7-187.1 °C
storage temp.:
__
SMILES string:
C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.CC(C)(C)c4ccc(OP(Oc5ccc(cc5C(C)(C)C)C(C)(C)C)Oc6c([Pd]Cl)cc(cc6C(C)(C)C)C(C)(C)C)c(c4)C(C)(C)C
InChI:
1S/C42H62O3P.C18H33P.ClH.Pd/c1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h19-23,25-27H,1-18H3;16-18H,1-15H2;1H;/q;;;+1/p-1
InChI key:
KSWCAUMOXBNXFL-UHFFFAOYSA-M
reaction suitability: __
Quality Level: 100
mp: __
storage temp.: __
SMILES string: O
InChI: 1S/H2O/h1H2
InChI key: XLYOFNOQVPJJNP-UHFFFAOYSA-N
reaction suitability:
__
Quality Level:
100
mp:
__
storage temp.:
__
SMILES string:
O
InChI:
1S/H2O/h1H2
InChI key:
XLYOFNOQVPJJNP-UHFFFAOYSA-N
reaction suitability: __
Quality Level: 100
mp: __
storage temp.: __
SMILES string: O
InChI: 1S/H2O/h1H2
InChI key: XLYOFNOQVPJJNP-UHFFFAOYSA-N
reaction suitability:
__
Quality Level:
100
mp:
__
storage temp.:
__
SMILES string:
O
InChI:
1S/H2O/h1H2
InChI key:
XLYOFNOQVPJJNP-UHFFFAOYSA-N