692778
(R,R)-DACH-naphthyl Trost ligand
95%
Manufacturer: Sigma Aldrich
CAS Number: 174810-09-4
Synonym(S): (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphino-1-naphthoyl)
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 MG | 692778-250-MG | In Stock | ₹ 9,212.08 |
| 1 G | 692778-1-G | In Stock | ₹ 35,181.25 |
692778 - 250 MG
In Stock
Quantity
1
Base Price: ₹ 9,212.08
GST (18%): ₹ 1,658.174
Total Price: ₹ 10,870.254
Quality Level
100
Assay
95%
form
powder
optical activity
[α]20/D +69.0°, c = 1 in methanol
mp
224-231 °C
SMILES string
O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2c(ccc3ccccc23)P(c4ccccc4)c5ccccc5)c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9
InChI
1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m1/s1
InChI key
VXFKMKXTPXVEMU-AWSIMMLFSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Strem, An Ascensus Company CAS# 174810-09-4. 2g. (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand. MFCD02684551 | Strem, An Ascensus Company | ₹ 50,884.24 | |
 | Strem, An Ascensus Company CAS# 174810-09-4. 100mg. (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand. MFCD02684551 | Strem, An Ascensus Company | ₹ 4,928.26 | |
 | Sigma Aldrich Fine Chemicals Biosciences (R,R)-DACH-naphthyl Trost ligand 95% | Purity: 95% | Mol Wt: 790.87 | 174810-09-4 | MFCD02684551 | 250MG | Sigma Aldrich Fine Chemicals Biosciences | ₹ 14,463.92 | |
 | 174810-09-4 | 1-Naphthalenecarboxamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- | A2B Chem | ₹ 1,112.28 - ₹ 2,994.60 |
Related Products
Description
- Application: Trost Ligands for Asymmetric Allylic Alkylation
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 95%
form: powder
optical activity: [α]20/D +69.0°, c = 1 in methanol
mp: 224-231 °C
SMILES string: O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2c(ccc3ccccc23)P(c4ccccc4)c5ccccc5)c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9
InChI: 1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m1/s1
InChI key: VXFKMKXTPXVEMU-AWSIMMLFSA-N
Quality Level:
100
Assay:
95%
form:
powder
optical activity:
[α]20/D +69.0°, c = 1 in methanol
mp:
224-231 °C
SMILES string:
O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2c(ccc3ccccc23)P(c4ccccc4)c5ccccc5)c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9
InChI:
1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m1/s1
InChI key:
VXFKMKXTPXVEMU-AWSIMMLFSA-N
Quality Level: 100
Assay: 95%
form: solid
optical activity: [α]20/D -66.0°, c = 1 in methanol
mp: 232-237 °C
SMILES string: O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2c(ccc3ccccc23)P(c4ccccc4)c5ccccc5)c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9
InChI: 1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m0/s1
InChI key: VXFKMKXTPXVEMU-ZYBCLOSLSA-N
Quality Level:
100
Assay:
95%
form:
solid
optical activity:
[α]20/D -66.0°, c = 1 in methanol
mp:
232-237 °C
SMILES string:
O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2c(ccc3ccccc23)P(c4ccccc4)c5ccccc5)c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9
InChI:
1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m0/s1
InChI key:
VXFKMKXTPXVEMU-ZYBCLOSLSA-N
Quality Level: 100
Assay: 95%
form: solid
optical activity: [α]20/D -134°, c = 1 in methanol
mp: 136-142 °C
SMILES string: O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
InChI: 1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m0/s1
InChI key: AXMSEDAJMGFTLR-ZAQUEYBZSA-N
Quality Level:
100
Assay:
95%
form:
solid
optical activity:
[α]20/D -134°, c = 1 in methanol
mp:
136-142 °C
SMILES string:
O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
InChI:
1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m0/s1
InChI key:
AXMSEDAJMGFTLR-ZAQUEYBZSA-N
Quality Level: 100
Assay: 95%
form: solid
optical activity: [α]20/D +131°, c = 1 in methanol
mp: 136-142 °C
SMILES string: O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
InChI: 1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m1/s1
InChI key: AXMSEDAJMGFTLR-XRSDMRJBSA-N
Quality Level:
100
Assay:
95%
form:
solid
optical activity:
[α]20/D +131°, c = 1 in methanol
mp:
136-142 °C
SMILES string:
O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
InChI:
1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m1/s1
InChI key:
AXMSEDAJMGFTLR-XRSDMRJBSA-N