697761

(R,R)-DIPAMP

95%

Manufacturer: Sigma Aldrich

CAS Number: 55739-58-7

Synonym(S): (R,R)-1,2-Bis[(2-methoxyphenyl)(phenylphosphino)]ethane, (R,R)-1,2-Ethanediylbis[(2-methoxyphenyl)phenylphosphine], (R,R)-Ethylenebis[(2-methoxyphenyl)phenylphosphine], [(1R,2R)-(−)-Bis[(2-methoxyphenyl)phenylphosphino]ethane]

Select a Size

Pack Size SKU Availability Price
100 MG 697761-100-MG In Stock ₹ 11,896.68
500 MG 697761-500-MG In Stock ₹ 42,249.98

697761 - 100 MG

₹ 11,896.68

In Stock

Quantity

1

Base Price: ₹ 11,896.68

GST (18%): ₹ 2,141.402

Total Price: ₹ 14,038.082

Quality Level

100

Assay

95%

form

solid

optical activity

[α]22/D −81°, c = 1 in chloroform

mp

102-106 °C (lit.)

SMILES string

COc1ccccc1P(CCP(c2ccccc2)c3ccccc3OC)c4ccccc4

InChI

1S/C28H28O2P2/c1-29-25-17-9-11-19-27(25)31(23-13-5-3-6-14-23)21-22-32(24-15-7-4-8-16-24)28-20-12-10-18-26(28)30-2/h3-20H,21-22H2,1-2H3/t31-,32-/m1/s1

InChI key

QKZWXPLBVCKXNQ-ROJLCIKYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-174-9179
Sigma Aldrich Fine Chemicals Biosciences (R,R)-DIPAMP 95% | Purity: 95% | Mol Wt: 458.47 | 55739-58-7 | MFCD05863546 | 100MG
Sigma Aldrich Fine Chemicals Biosciences ₹ 18,656.36
AI52493
55739-58-7 | (R,R)-Dipamp
A2B Chem ₹ 4,363.56 - ₹ 9,582.72

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Description

  • Application: (R, R)-DIPAMP can be used:As a catalyst in the enantioselective [3+2] cycloaddition of γ-substituted allenoates with β-perfluoroalkyl enones[1] and 3-butynoates with electron-deficient olefins[2] to yield substituted cyclopentenes.To prepare its rhodium metal complexes, which are used as catalysts in asymmetric hydrogenation reactions.[3][4]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335,H413

Precautionary Statements

P273 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

697761

95%...


Quality Level:
100

Assay:
95%

form:
solid

optical activity:
[α]22/D −81°, c = 1 in chloroform

mp:
102-106 °C (lit.)

SMILES string:
COc1ccccc1P(CCP(c2ccccc2)c3ccccc3OC)c4ccccc4

InChI:
1S/C28H28O2P2/c1-29-25-17-9-11-19-27(25)31(23-13-5-3-6-14-23)21-22-32(24-15-7-4-8-16-24)28-20-12-10-18-26(28)30-2/h3-20H,21-22H2,1-2H3/t31-,32-/m1/s1

InChI key:
QKZWXPLBVCKXNQ-ROJLCIKYSA-N

Img

Sigma Aldrich

69785

~90% (T)...


Quality Level:
200

Assay:
~90% (T)

form:
liquid

optical activity:
__

mp:
__

SMILES string:
CC(O)C(O)=O

InChI:
1S/C3H6O3/c1-2(4)3(5)6/h2,4H,1H3,(H,5,6)

InChI key:
JVTAAEKCZFNVCJ-UHFFFAOYSA-N

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Sigma Aldrich

697869

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Quality Level:
100

Assay:
97%

form:
liquid

optical activity:
__

mp:
__

SMILES string:
COC(=O)c1ccnc(F)c1

InChI:
1S/C7H6FNO2/c1-11-7(10)5-2-3-9-6(8)4-5/h2-4H,1H3

InChI key:
MTZKFHSYUSUUIU-UHFFFAOYSA-N

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Sigma Aldrich

697885

97%...


Quality Level:
100

Assay:
97%

form:
powder

optical activity:
__

mp:
78-82 °C

SMILES string:
Brc1ccccc1-c2ccccc2Br

InChI:
1S/C12H8Br2/c13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14/h1-8H

InChI key:
DRKHIWKXLZCAKP-UHFFFAOYSA-N