223670

Bis(cyclopentadienyl)zirconium(IV) chloride hydride

95%

Manufacturer: Sigma Aldrich

CAS Number: 37342-97-5

Synonym(S): Di(cyclopentadienyl)zirconium(IV) chloride hydride, Schwartz’ reagent, Zirconocene chloride hydride

Select a Size

Pack Size SKU Availability Price
1 G 223670-1-G In Stock ₹ 4,308.35
5 G 223670-5-G In Stock ₹ 14,451.38
25 G 223670-25-G In Stock ₹ 59,201.93

223670 - 1 G

₹ 4,308.35

In Stock

Quantity

1

Base Price: ₹ 4,308.35

GST (18%): ₹ 775.503

Total Price: ₹ 5,083.853

Quality Level

100

Assay

95%

form

powder

reaction suitability

core: zirconiumreagent type: catalystreagent type: reductant

SMILES string

[H][Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.ClH.Zr.H/c2*1-2-4-5-3-1;;;/h2*1-5H;1H;;/q;;;+1;/p-1

InChI key

PSYHEBZUPSHSKK-UHFFFAOYSA-M

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Description

  • General description: Bis(cyclopentadienyl)zirconium(IV) chloride hydride, also known as Schwartz′s reagent, is utilized as a catalyst in in olefin polymerization.[1]
  • Application: Bis(cyclopentadienyl)zirconium(IV) chloride hydride can be used:To convert amides to aldehydes.[2]As a reagent for the functionalization of olefins and alkynes.[3]As a reducing agent in the preparation of (E)-vinyl organochalcogenides.[4]To prepare a dioxaborolane derivative, which is a key intermediate for the synthesis of bridged-nicotine analogs.[5]

SAFETY INFORMATION

Pictograms

GHS02,GHS05

Signal Word

Danger

Hazard Statements

H261,H314

Precautionary Statements

P223 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Skin Corr. 1B - Water-react 2

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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form:
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reaction suitability:
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SMILES string:
[H][Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI:
1S/2C5H5.ClH.Zr.H/c2*1-2-4-5-3-1;;;/h2*1-5H;1H;;/q;;;+1;/p-1

InChI key:
PSYHEBZUPSHSKK-UHFFFAOYSA-M

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SMILES string:
Cl[Pd]Cl.N#Cc1ccccc1.N#Cc2ccccc2

InChI:
1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

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InChI key:
PDTKOBRZPAIMRD-UHFFFAOYSA-O