Tebbe reagent solution
0.5 M in toluene
Manufacturer: Sigma Aldrich
CAS Number: 67719-69-1
Synonym(S): Bis(cyclopentadienyl)-μ-chloro(dimethylaluminum)-μ-methylenetitanium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 25 ML | 380237-25-ML | In Stock | ₹ 17,471.55 |
| 100 ML | 380237-100-ML | In Stock | ₹ 66,411.38 |
380237 - 25 ML
In Stock
Quantity
1
Base Price: ₹ 17,471.55
GST (18%): ₹ 3,144.879
Total Price: ₹ 20,616.429
form
liquid
Quality Level
100
reaction suitability
reaction type: C-C Bond Formation
concentration
0.5 M in toluene
density
0.927 g/mL at 25 °C
SMILES string
[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.C[Al](C)C[Ti]Cl
InChI
1S/2C5H5.2CH3.CH2.Al.ClH.Ti/c2*1-2-4-5-3-1;;;;;;/h2*1-5H;2*1H3;1H2;;1H;/q;;;;;;;+1/p-1
InChI key
QEJAQNUJXFLWSP-UHFFFAOYSA-M
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Sigma Aldrich Fine Chemicals Biosciences Tebbe reagent solution 0.5 M in toluene | 67719-69-1 | MFCD00151575 | 4X25ML | Sigma Aldrich Fine Chemicals Biosciences | ₹ 51,027.98 | |
 | 67719-69-1 | Tebbe reagent | A2B Chem | ₹ 33,282.84 - ₹ 56,127.36 |
Related Products
Description
- General description: Tebbe reagent is a Lewis acid stabilized organometallic compound, which is used to transform carbonyl groups into β-substituted methylenes. It also reacts with a wide range of carbonyl compounds, including esters, amides, and lactones to yield corresponding olefins.[1][2]
- Application: Tebbe reagent can be used: For the conversion of carbonyl groups of chlorophyll derivatives into the corresponding exo-methylene (or vinylidene) groups.[2]In the synthesis of β-C-glycosides from 3-OH glycol esters.[3]As a versatile methylenation reagent for the conversion of ketones and aldehydes to olefins. It offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers.[4]To olefinate aldehydes.[5]To methylenate a chiral polyhydroxyketone with high diasteroselctivity.[6]
- Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
- Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
Target Organs
Central nervous system, Respiratory system
WGK
WGK 3
Flash Point(F)
39.2 °F
Flash Point(C)
4 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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form: liquid
Quality Level: 100
reaction suitability: reaction type: C-C Bond Formation
concentration: 0.5 M in toluene
density: 0.927 g/mL at 25 °C
SMILES string: [CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.C[Al](C)C[Ti]Cl
InChI: 1S/2C5H5.2CH3.CH2.Al.ClH.Ti/c2*1-2-4-5-3-1;;;;;;/h2*1-5H;2*1H3;1H2;;1H;/q;;;;;;;+1/p-1
InChI key: QEJAQNUJXFLWSP-UHFFFAOYSA-M
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