499021

(2-Naphthylmethyl)zinc bromide solution

0.5 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 152329-44-7

Select a Size

Pack Size SKU Availability Price
50 ML 499021-50-ML In Stock ₹ 17,666.40

499021 - 50 ML

₹ 17,666.40

In Stock

Quantity

1

Base Price: ₹ 17,666.40

GST (18%): ₹ 3,179.952

Total Price: ₹ 20,846.352

Quality Level

100

concentration

0.5 M in THF

density

0.978 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Br[Zn]Cc1ccc2ccccc2c1

InChI

1S/C11H9.BrH.Zn/c1-9-6-7-10-4-2-3-5-11(10)8-9;;/h2-8H,1H2;1H;/q;;+1/p-1

InChI key

IKDINBHMSAHXCA-UHFFFAOYSA-M

Other Options

Image Product Name Manufacturer Price Range
50-269-5268
eMolecules​ Synthonix (2-Naphthylmethyl)zinc bromide 0.50 M in THF 25ml 627353712 N73099 152329-44-7 [null] 286.480 C11H9BrZn
eMolecules​ ₹ 28,211.70
AE83713
152329-44-7 | (2-Naphthyl)methylzinc bromide
A2B Chem ₹ 36,619.68 - ₹ 61,346.52

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Description

  • General description: (2-Naphthylmethyl)zinc bromide is an organozinc halide, which is typically used as a reagent in Negishi cross-coupling reactions. In this process, the organozinc halide reacts with organic halides or triflates to form a carbon-carbon bond in the presence of a Pd catalyst.[1][2]
  • Application: (2-Naphthylmethyl)zinc bromide can be used as a reagent for the synthesis of: 4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile from 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile using Pd catalyst.[2] (E)-stilbene, (2,2′-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]) from 1,4-benzenedicarboxaldehyde in the presence of Pd catalyst and a silylating agent.[3]
  • Legal Information: Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS07

Signal Word

Danger

Hazard Statements

H225,H319,H335,H336,H351

Precautionary Statements

P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 3

Flash Point(F)

1.4 °F

Flash Point(C)

-17 °C

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100

concentration:
0.5 M in THF

density:
0.978 g/mL at 25 °C

storage temp.:
2-8°C

SMILES string:
Br[Zn]Cc1ccc2ccccc2c1

InChI:
1S/C11H9.BrH.Zn/c1-9-6-7-10-4-2-3-5-11(10)8-9;;/h2-8H,1H2;1H;/q;;+1/p-1

InChI key:
IKDINBHMSAHXCA-UHFFFAOYSA-M

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