520322

2-Cyanobenzylzinc bromide solution

0.5 M in THF

Manufacturer: Sigma Aldrich

CAS Number: 199465-66-2

Select a Size

Pack Size SKU Availability Price
50 ML 520322-50-ML In Stock ₹ 29,909.48

520322 - 50 ML

₹ 29,909.48

In Stock

Quantity

1

Base Price: ₹ 29,909.48

GST (18%): ₹ 5,383.706

Total Price: ₹ 35,293.186

Quality Level

100

concentration

0.5 M in THF

density

0.993 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Br[Zn]Cc1ccccc1C#N

InChI

1S/C8H6N.BrH.Zn/c1-7-4-2-3-5-8(7)6-9;;/h2-5H,1H2;1H;/q;;+1/p-1

InChI key

LQRNYQAXNZETFP-UHFFFAOYSA-M

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Description

  • Application: 2-Cyanobenzylzinc bromide can be used as a reactant: In the metal-catalyzed Negishi cross-coupling reactions to prepare aryl or heteroaryl derivatives via carbon-carbon bond formation.[1] To synthesize 4-(2-Cyanobenzyl)-3′-(trifluoromethyl)biphenyl by reacting with aryl nonaflate in the presence of Pd(dba)2 as a catalyst.[2] To prepare 2-[(2-cyanophenyl)methyl] benzamide by treating with 2-iodobenzamide using a nickel catalyst.[3]
  • Legal Information: Product of Rieke Metals, Inc. Rieke is a registered trademark of Rieke Metals, Inc.

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS07

Signal Word

Danger

Hazard Statements

H225,H319,H335,H336,H351

Precautionary Statements

P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH014,EUH019

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

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SMILES string:
Br[Zn]Cc1ccccc1C#N

InChI:
1S/C8H6N.BrH.Zn/c1-7-4-2-3-5-8(7)6-9;;/h2-5H,1H2;1H;/q;;+1/p-1

InChI key:
LQRNYQAXNZETFP-UHFFFAOYSA-M

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InChI:
1S/C5H12FN2.F6P/c1-7(2)5(6)8(3)4;1-7(2,3,4,5)6/h1-4H3;/q+1;-1

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ZAVXOOLKAGPJPI-UHFFFAOYSA-N

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