695157

Bis(3,5-dimethylphenyl)phosphine

Manufacturer: Sigma Aldrich

CAS Number: 71360-06-0

Select a Size

Pack Size SKU Availability Price
500 MG 695157-500-MG In Stock ₹ 23,641.80

695157 - 500 MG

₹ 23,641.80

In Stock

Quantity

1

Base Price: ₹ 23,641.80

GST (18%): ₹ 4,255.524

Total Price: ₹ 27,897.324

form

liquid

Quality Level

100

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

refractive index

n20/D 1.599

density

1.017 g/mL at 25 °C

functional group

phosphine

SMILES string

Cc1cc(C)cc(Pc2cc(C)cc(C)c2)c1

InChI

1S/C16H19P/c1-11-5-12(2)8-15(7-11)17-16-9-13(3)6-14(4)10-16/h5-10,17H,1-4H3

InChI key

GPFIUEZTNRNFGD-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-175-6670
Sigma Aldrich Fine Chemicals Biosciences Bis(3,5-dimethylphenyl)phosphine | 71360-06-0 | MFCD01074629 | 500MG
Sigma Aldrich Fine Chemicals Biosciences ₹ 27,041.24
50-216-8661
eMolecules​ Bis(3,5-dimethylphenyl)phosphine, 98% (10wt% in hexanes) | 71360-06-0 | MFCD01074629 | 5g
eMolecules​ ₹ 34,130.74
AB71199
71360-06-0 | Bis(3,5-dimethylphenyl)phosphine
A2B Chem ₹ 2,310.12 - ₹ 63,143.28

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Description

  • Application: Bis(3,5-dimethylphenyl)phosphine can be used as a reactant to prepare: Iron(II) chiral diimine diphosphine complexes as catalysts for the asymmetric transfer hydrogenation of ketones.[1] The complex of iridium with biphenol phosphite-phosphine bidentate ligand as an asymmetric catalyst for the hydrogenation of N-arylimines.[2] Chiral phosphines with excellent stereoselectivity by 1, 4 addition reaction with α,β-unsaturated aldehydes using a palladium catalyst.[3]
  • Legal Information: Product of Kanata Chemical Technologies, Inc.

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302

Hazard Classifications

Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

>230.0 °F

Flash Point(C)

> 110 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

695157

--


form:
liquid

Quality Level:
100

reaction suitability:
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

refractive index:
n20/D 1.599

density:
1.017 g/mL at 25 °C

functional group:
phosphine

SMILES string:
Cc1cc(C)cc(Pc2cc(C)cc(C)c2)c1

InChI:
1S/C16H19P/c1-11-5-12(2)8-15(7-11)17-16-9-13(3)6-14(4)10-16/h5-10,17H,1-4H3

InChI key:
GPFIUEZTNRNFGD-UHFFFAOYSA-N

Img

Sigma Aldrich

695173

--


form:
powder

Quality Level:
100

reaction suitability:
core: goldreagent type: catalyst

refractive index:
__

density:
__

functional group:
__

SMILES string:
Cl[Au]1(Cl)OC(=O)C2=[N]1C=CC=C2

InChI:
1S/C6H5NO2.Au.2ClH/c8-6(9)5-3-1-2-4-7-5;;;/h1-4H,(H,8,9);;2*1H/q;+3;;/p-3

InChI key:
PKAWSKSRAJXTIH-UHFFFAOYSA-K

Img

Sigma Aldrich

695211

--


form:
solid

Quality Level:
100

reaction suitability:
reagent type: ligandreaction type: Arylationsreagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reactionreagent type: ligandreaction type: Heck Reactionreagent type: ligandreaction type: Reductions

refractive index:
__

density:
__

functional group:
phosphine

SMILES string:
Cc1ccccc1-c2ccccc2P(C(C)(C)C)C(C)(C)C

InChI:
1S/C21H29P/c1-16-12-8-9-13-17(16)18-14-10-11-15-19(18)22(20(2,3)4)21(5,6)7/h8-15H,1-7H3

InChI key:
UJONYAVMBYXBJQ-UHFFFAOYSA-N

Img

Sigma Aldrich

695254

--


form:
powder

Quality Level:
200

reaction suitability:
reagent type: reductant

refractive index:
__

density:
__

functional group:
__

SMILES string:
[BH4-].[BH4-].[Ca++]

InChI:
1S/2BH4.Ca/h2*1H4;/q2*-1;+2

InChI key:
MOUPUCLGEWXWHJ-UHFFFAOYSA-N