324620
Lithium bis(trimethylsilyl)amide
97%
Manufacturer: Sigma Aldrich
CAS Number: 4039-32-1
Synonym(S): Hexamethyldisilazane lithium salt
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 10 G | 324620-10-G | In Stock | ₹ 8,952.28 |
| 50 G | 324620-50-G | In Stock | ₹ 11,203.88 |
| 250 G | 324620-250-G | In Stock | ₹ 37,173.05 |
324620 - 10 G
In Stock
Quantity
1
Base Price: ₹ 8,952.28
GST (18%): ₹ 1,611.41
Total Price: ₹ 10,563.69
Quality Level
200
Assay
97%
form
solid
density
0.860 g/mL at 25 °C (lit.)
SMILES string
[Li]N([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key
YNESATAKKCNGOF-UHFFFAOYSA-N
Other Options
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Description
- General description: Lithium bis(trimethylsilyl)amide is a non-nucleophilic strong Brønsted base, which is generally soluble in most of the nonpolar organic solvents. It is most commonly employed in organic reactions.[1][2]
- Application: Base employed in generating enolates for the preparation of lactone precursors,[3] pyranones,[4] and cyclohexanes.[5]Used to catalyze the addition of phosphine P-H bonds to carbodiimides leading to phosphaguanidines.[6] Also used in a novel three-step synthesis of disubstituted 1,2,5-thiadiazoles.[7]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P235 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Classifications
Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B
Supplementary Hazards
EUH014
WGK
WGK 2
Flash Point(F)
62.6 °F
Flash Point(C)
17 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Quality Level: 200
Assay: 97%
form: solid
density: 0.860 g/mL at 25 °C (lit.)
SMILES string: [Li]N([Si](C)(C)C)[Si](C)(C)C
InChI: 1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key: YNESATAKKCNGOF-UHFFFAOYSA-N
Quality Level:
200
Assay:
97%
form:
solid
density:
0.860 g/mL at 25 °C (lit.)
SMILES string:
[Li]N([Si](C)(C)C)[Si](C)(C)C
InChI:
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key:
YNESATAKKCNGOF-UHFFFAOYSA-N
Quality Level: 100
Assay: ≥98% dry basis (complexometric)
form: solid (fine)
density: __
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Quality Level:
100
Assay:
≥98% dry basis (complexometric)
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solid (fine)
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Assay: ≥95% (HPLC)
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100
Assay:
≥95% (HPLC)
form:
oil
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