577928
Lithium bis(trimethylsilyl)amide solution
1 M in toluene
Manufacturer: Sigma Aldrich
CAS Number: 4039-32-1
Synonym(S): LiHMDS, Hexamethyldisilazane lithium salt
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 ML | 577928-100-ML | In Stock | ₹ 4,459.90 |
| 800 ML | 577928-800-ML | In Stock | ₹ 21,065.45 |
577928 - 100 ML
In Stock
Quantity
1
Base Price: ₹ 4,459.90
GST (18%): ₹ 802.782
Total Price: ₹ 5,262.682
Quality Level
200
concentration
1 M in toluene
density
0.860 g/mL at 25 °C
SMILES string
[Li]N([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key
YNESATAKKCNGOF-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Lithium bis(trimethylsilyl)amide solution | Sigma Aldrich | ₹ 1,032.71 - ₹ 36,913.25 | |
| | Lithium bis(trimethylsilyl)amide | Sigma Aldrich | ₹ 8,952.28 - ₹ 37,173.05 | |
| | Lithium bis(trimethylsilyl)amide solution | Sigma Aldrich | ₹ 11,636.88 - ₹ 76,093.43 | |
| | Lithium bis(trimethylsilyl)amide solution | Sigma Aldrich | ₹ 4,459.90 | |
| | Lithium bis(trimethylsilyl)amide solution | Sigma Aldrich | ₹ 5,661.48 | |
 | Lithium bis(trimethylsilyl)amide | Sigma Aldrich | ₹ 2,565.53 - ₹ 18,489.10 |
Related Products
Description
- General description: Lithium bis(trimethylsilyl)amide solution (LiHMDS) is generally used in organic synthesis as a non-nucleophilic strong Bronsted base.[1]
- Application: LiHMDS can be used as a reagent: In the deprotonation and nucleophilic difluoromethylation reactions.[2][3] To synthesize isoquinoline derivatives by the addition of N-iodosuccinimide (NIS) to the α-benzyl tosylmethyl isocyanides.[4] To prepare arylboronic acid pinacol esters by the reaction of aryl fluorides with bis(pinacolato)diboron via palladium-catalyzed cross-coupling reaction.[5]
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Self-heat. 1 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
Target Organs
Central nervous system
Supplementary Hazards
EUH014
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 200
concentration: 1 M in toluene
density: 0.860 g/mL at 25 °C
SMILES string: [Li]N([Si](C)(C)C)[Si](C)(C)C
InChI: 1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key: YNESATAKKCNGOF-UHFFFAOYSA-N
Quality Level:
200
concentration:
1 M in toluene
density:
0.860 g/mL at 25 °C
SMILES string:
[Li]N([Si](C)(C)C)[Si](C)(C)C
InChI:
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key:
YNESATAKKCNGOF-UHFFFAOYSA-N
Quality Level: 300
concentration: __
density: __
SMILES string: __
InChI: __
InChI key: __
Quality Level:
300
concentration:
__
density:
__
SMILES string:
__
InChI:
__
InChI key:
__
Quality Level: 100
concentration: __
density: __
SMILES string: __
InChI: 1S/C4H5N/c1-2-4-5-3-1/h1-5H
InChI key: KAESVJOAVNADME-UHFFFAOYSA-N
Quality Level:
100
concentration:
__
density:
__
SMILES string:
__
InChI:
1S/C4H5N/c1-2-4-5-3-1/h1-5H
InChI key:
KAESVJOAVNADME-UHFFFAOYSA-N
Quality Level: 100
concentration: __
density: 1.4160 g/mL at 25 °C (lit.)
SMILES string: Nc1ccc(cc1Cl)C(F)(F)F
InChI: 1S/C7H5ClF3N/c8-5-3-4(7(9,10)11)1-2-6(5)12/h1-3H,12H2
InChI key: MBBUTABXEITVNY-UHFFFAOYSA-N
Quality Level:
100
concentration:
__
density:
1.4160 g/mL at 25 °C (lit.)
SMILES string:
Nc1ccc(cc1Cl)C(F)(F)F
InChI:
1S/C7H5ClF3N/c8-5-3-4(7(9,10)11)1-2-6(5)12/h1-3H,12H2
InChI key:
MBBUTABXEITVNY-UHFFFAOYSA-N