715468

Barium tert-butoxide

85%

Manufacturer: Sigma Aldrich

CAS Number: 24363-36-8

Synonym(S): Barium di-t-butoxide

Select a Size

Pack Size SKU Availability Price
1 G 715468-1-G In Stock ₹ 6,884.70

715468 - 1 G

₹ 6,884.70

In Stock

Quantity

1

Base Price: ₹ 6,884.70

GST (18%): ₹ 1,239.246

Total Price: ₹ 8,123.946

Quality Level

100

Assay

85%

form

powder

mp

>200 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)O[Ba]OC(C)(C)C

InChI

1S/2C4H9O.Ba/c2*1-4(2,3)5;/h2*1-3H3;/q2*-1;+2

InChI key

SLPLCLDJTNLWPW-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
715468
Barium tert-butoxide
Sigma Aldrich ₹ 6,884.70

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Description

  • General description: Barium tert-butoxide is a Brønsted base catalyst that can be used as a precursor of various barium catalysts like barium aryloxide. It can also be used in the preparation of barium diphenylmethanide, applicable in the organometallic chemistry.[1]
  • Application: Barium tert-butoxide can be used:As a catalyst along with various phenolic ligands in the aldol reactions of amides with aldehydes and ketones.[2]To prepare yttrium and copper metal complexes by reacting with Y(thd)3 and Cu(thd)2, where “thd” is 2,2,6,6-tetramethylheptane-3,5-dione.[3]As an initiator along with an alkyl lithium in the butadiene copolymerization reaction.[4]In the iridium catalyzed allylic alkylation of non-stabilized enolates.[5]

SAFETY INFORMATION

Pictograms

GHS02,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H228,H314,H335

Precautionary Statements

P210 - P240 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Flam. Sol. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH014

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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715468

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Quality Level:
100

Assay:
85%

form:
powder

mp:
>200 °C

storage temp.:
2-8°C

SMILES string:
CC(C)(C)O[Ba]OC(C)(C)C

InChI:
1S/2C4H9O.Ba/c2*1-4(2,3)5;/h2*1-3H3;/q2*-1;+2

InChI key:
SLPLCLDJTNLWPW-UHFFFAOYSA-N

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Assay:
97%

form:
solid

mp:
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storage temp.:
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SMILES string:
CC1(C)OB(OC1(C)C)c2cnc3nccnc3c2

InChI:
1S/C13H16BN3O2/c1-12(2)13(3,4)19-14(18-12)9-7-10-11(17-8-9)16-6-5-15-10/h5-8H,1-4H3

InChI key:
QLYMAIYXJXENHJ-UHFFFAOYSA-N

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100

Assay:
≥94%

form:
solid

mp:
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SMILES string:
CN(C)C(=O)c1ccc(cc1)B(O)O

InChI:
1S/C9H12BNO3/c1-11(2)9(12)7-3-5-8(6-4-7)10(13)14/h3-6,13-14H,1-2H3

InChI key:
QJYYVSIRDJVQJW-UHFFFAOYSA-N

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Assay:
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form:
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mp:
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storage temp.:
__

SMILES string:
CN[C@@H]([C@H](NC)c1ccccc1)c2ccccc2

InChI:
1S/C16H20N2/c1-17-15(13-9-5-3-6-10-13)16(18-2)14-11-7-4-8-12-14/h3-12,15-18H,1-2H3/t15-,16-/m1/s1

InChI key:
BTHYVQUNQHWNLS-HZPDHXFCSA-N