79421

Phosphazene base P4-t-Bu solution

~0.8 M in hexane

Manufacturer: Sigma Aldrich

CAS Number: 111324-04-0

Synonym(S): 1-tert-Butyl-4,4,4-tris(dimethylamino)-2,2-bis[tris(dimethylamino)-phosphoranylidenamino]-2λ5,4λ5-catenadi(phosphazene)

Select a Size

Pack Size SKU Availability Price
1 ML 79421-1-ML In Stock ₹ 8,703.30
5 ML 79421-5-ML In Stock ₹ 28,556.35
25 ML 79421-25-ML In Stock ₹ 90,215.55

79421 - 1 ML

₹ 8,703.30

In Stock

Quantity

1

Base Price: ₹ 8,703.30

GST (18%): ₹ 1,566.594

Total Price: ₹ 10,269.894

form

liquid

Quality Level

100

concentration

~0.8 M in hexane

density

0.850-0.875 g/mL at 20 °C

SMILES string

CN(C)P(=NP(=NC(C)(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C

InChI

1S/C22H63N13P4/c1-22(2,3)23-36(24-37(27(4)5,28(6)7)29(8)9,25-38(30(10)11,31(12)13)32(14)15)26-39(33(16)17,34(18)19)35(20)21/h1-21H3

InChI key

NSRBCQCXZAYQHF-UHFFFAOYSA-N

Other Options

Image Product Name Manufacturer Price Range
50-1769-151
Sigma Aldrich Fine Chemicals Biosciences Phosphazene base P4-t-Bu solution ~0.8 M in hexane | 111324-04-0 | MFCD00145114 | 1ML
Sigma Aldrich Fine Chemicals Biosciences ₹ 14,463.92
50-1769-153
Sigma Aldrich Fine Chemicals Biosciences Phosphazene base P4-t-Bu solution ~0.8 M in hexane | 111324-04-0 | MFCD00145114 | 5ML
Sigma Aldrich Fine Chemicals Biosciences ₹ 45,278.35
79421
Phosphazene base P4-t-Bu solution
Sigma Aldrich ₹ 8,703.30 - ₹ 90,215.55
AB78319
111324-04-0 | (tert-Butylimino)tris((tris(dimethylamino)phosphoranylidene)amino)phosphorane
A2B Chem ₹ 5,732.52 - ₹ 93,003.72

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Description

  • Application: Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen–Bases
  • Caution: Product crystallizes out of solution, can be redissolved on heating to 40°C.
  • Other Notes: Extremely strong, hindered, neutral nitrogen base; it is about 1018 times more basic than DBU [pKa (DMSO) 30.25]. Stable to hydrolysis and unaffected by alkylating agents[1][2]; Base for enolate formation and stereoselective alkylation[3]

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05,GHS07

Signal Word

Danger

Hazard Statements

H225,H304,H314,H336,H361f,H372,H412

Precautionary Statements

P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3

Target Organs

Central nervous system, Nervous system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Compare Similar Items

Show Difference

Img

Sigma Aldrich

79421

~0.8 M in hexane...


form:
liquid

Quality Level:
100

concentration:
~0.8 M in hexane

density:
0.850-0.875 g/mL at 20 °C

SMILES string:
CN(C)P(=NP(=NC(C)(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C

InChI:
1S/C22H63N13P4/c1-22(2,3)23-36(24-37(27(4)5,28(6)7)29(8)9,25-38(30(10)11,31(12)13)32(14)15)26-39(33(16)17,34(18)19)35(20)21/h1-21H3

InChI key:
NSRBCQCXZAYQHF-UHFFFAOYSA-N

Img

Sigma Aldrich

794228

95%...


form:
solid

Quality Level:
100

concentration:
__

density:
__

SMILES string:
O=S(O[Pd]C1=CC=CC=C1C2=CC=CC=C2N)(C)=O.C3(P(C4=CC=CC=C4)C5=CC=CC=C5)=C(OC(C(P(C6=CC=CC=C6)C7=CC=CC=C7)=CC=C8)=C8N9)C9=CC=C3

InChI:
1S/C36H27NOP2.C12H10N.CH4O3S.Pd/c1-5-15-27(16-6-1)39(28-17-7-2-8-18-28)33-25-13-23-31-35(33)38-36-32(37-31)24-14-26-34(36)40(29-19-9-3-10-20-29)30-21-11-4-12-22-30;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h1-26,37H;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

InChI key:
RKPGNKWNXMCYQX-UHFFFAOYSA-M

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Sigma Aldrich

794279

--


form:
solid

Quality Level:
100

concentration:
__

density:
__

SMILES string:
Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7

InChI:
1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1

InChI key:
QVGJKVLYWZGANE-UHFFFAOYSA-M

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Sigma Aldrich

794287

--


form:
solid

Quality Level:
100

concentration:
__

density:
__

SMILES string:
CC(C(C)(C)O1)(C)OB1CB2OC(C)(C)C(C)(C)O2

InChI:
1S/C13H26B2O4/c1-10(2)11(3,4)17-14(16-10)9-15-18-12(5,6)13(7,8)19-15/h9H2,1-8H3

InChI key:
MQYZGGWWHUGYDR-UHFFFAOYSA-N