Chlorodicyclohexylphosphine
97%
Manufacturer: Sigma Aldrich
CAS Number: 16523-54-9
Synonym(S): Dicyclohexylchlorophosphine, Dicyclohexylphosphine chloride, Dicyclohexylphosphinous chloride
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 481408-1-G | In Stock | ₹ 5,163.53 |
| 5 G | 481408-5-G | In Stock | ₹ 9,493.53 |
481408 - 1 G
In Stock
Quantity
1
Base Price: ₹ 5,163.53
GST (18%): ₹ 929.435
Total Price: ₹ 6,092.965
Quality Level
100
Assay
97%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand
refractive index
n20/D 1.533 (lit.)
bp
165 °C/12 mmHg (lit.)
density
1.054 g/mL at 25 °C (lit.)
functional group
phosphine
SMILES string
ClP(C1CCCCC1)C2CCCCC2
InChI
1S/C12H22ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
InChI key
AKJFBIZAEPTXIL-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
 | Strem, An Ascensus Company Dicyclohexylchlorophosphine, min. 98%; [16523-54-9]; (C6H11)2PCl; Mol Wt:232.74; Color & Form: colorless to pale yellow, cloudy liq.; Size: 1g | Strem, An Ascensus Company | ₹ 7,289.71 | |
 | Sigma Aldrich Fine Chemicals Biosciences Chlorodicyclohexylphosphine 97% | 16523-54-9 | MFCD00014294 | 1G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 9,024.01 | |
 | eMolecules Ambeed / Chlorodicyclohexylphosphine / 1g / 589771693 / A878784 / / 16523-54-9 / MFCD00014294 / 232.730 / C12H22ClP | eMolecules | ₹ 2,767.01 | |
| | Sigma Aldrich Fine Chemicals Biosciences Chlorodicyclohexylphosphine 97% | 16523-54-9 | MFCD00014294 | 5G | Sigma Aldrich Fine Chemicals Biosciences | ₹ 30,604.81 | |
 | 16523-54-9 | Dicyclohexylchlorophosphine | A2B Chem | ₹ 855.60 - ₹ 19,251.00 |
Related Products
Description
- Application: Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of: 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis−Arbuzov type rearrangements.[1]1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.[2]It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide [3], phosphino substituted N-aryl pyrroles [4], di-tert-butyl((dicyclohexylphosphino)methyl)phosphine [5], dicyclohexylcyclopentylphosphine[6]. These ligands are used in Pd-catalyzed cross-coupling reactions.
SAFETY INFORMATION
Pictograms
Signal Word
Danger
Hazard Statements
Precautionary Statements
P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Supplementary Hazards
EUH014
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Compare Similar Items
Show Difference
Quality Level: 100
Assay: 97%
reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand
refractive index: n20/D 1.533 (lit.)
bp: 165 °C/12 mmHg (lit.)
density: 1.054 g/mL at 25 °C (lit.)
functional group: phosphine
SMILES string: ClP(C1CCCCC1)C2CCCCC2
InChI: 1S/C12H22ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
InChI key: AKJFBIZAEPTXIL-UHFFFAOYSA-N
Quality Level: 200
Assay: __
reaction suitability: reagent type: catalystcore: zincreagent type: oxidant
refractive index: __
bp: __
density: 1.57 g/mL at 25 °C (lit.)
functional group: __
SMILES string: [Zn++].[O-][O-]
InChI: 1S/O2.Zn/c1-2;/q-2;+2
InChI key: IPTOGCUGCFHDSS-UHFFFAOYSA-N
Quality Level: 200
Assay: __
reaction suitability: reagent type: catalystcore: zincreagent type: oxidant
refractive index: __
bp: __
density: 1.57 g/mL at 25 °C (lit.)
functional group: __
SMILES string: [Zn++].[O-][O-]
InChI: 1S/O2.Zn/c1-2;/q-2;+2
InChI key: IPTOGCUGCFHDSS-UHFFFAOYSA-N
