[(S,S)-Teth-TsDpen RuCl]
Manufacturer: Sigma Aldrich
CAS Number: 851051-43-9
Synonym(S): stereoisomer of Chloro[N-[(1S,2S)-1,2-diphenyl-2-[(R)-[3-(η6-phenyl)propyl]amino-κN]ethyl]-4-methylbenzenesulfonamidato-κN]ruthenium
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| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 752800-100-MG | In Stock | ₹ 12,554.10 |
| 500 MG | 752800-500-MG | In Stock | ₹ 26,795.40 |
752800 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 12,554.10
GST (18%): ₹ 2,259.738
Total Price: ₹ 14,813.838
form
solid
Quality Level
100
optical activity
[α]22/D +339°, c = 0.5% in chloroform
reaction suitability
core: rutheniumreagent type: catalyst
mp
260-268 °C
storage temp.
2-8°C
SMILES string
Cc1ccc(cc1)S(=O)(=O)N2[C@H]([C@@H]([N@@H](CCCc3ccccc3)[Ru]2Cl)c4ccccc4)c5ccccc5
InChI
1S/C30H31N2O2S.ClH.Ru/c1-24-19-21-28(22-20-24)35(33,34)32-30(27-17-9-4-10-18-27)29(26-15-7-3-8-16-26)31-23-11-14-25-12-5-2-6-13-25;;/h2-10,12-13,15-22,29-31H,11,14,23H2,1H3;1H;/q-1;;+2/p-1/t29-,30-;;/m0../s1
InChI key
MDABGVLQRDDWLY-ARDORAJISA-M
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Description
- Application: [(S,S)-Teth-TsDpen RuCl] is a catalyst for the asymmetric hydrogenation of ketones. It can be used as a catalyst:In the reduction of a ketone intermediate for the synthesis of esketamine.[1]In asymmetric hydrogenation of acetylenic ketones.[2]For the preparation of (3S,6S)-1,8-diphenylocta-1,7-diyne-3,6-diol starting from 1,8-diphenylocta-1,7-diyne-3,6-dione.[3]
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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form: solid
Quality Level: 100
optical activity: [α]22/D +339°, c = 0.5% in chloroform
reaction suitability: core: rutheniumreagent type: catalyst
mp: 260-268 °C
storage temp.: 2-8°C
SMILES string: Cc1ccc(cc1)S(=O)(=O)N2[C@H]([C@@H]([N@@H](CCCc3ccccc3)[Ru]2Cl)c4ccccc4)c5ccccc5
InChI: 1S/C30H31N2O2S.ClH.Ru/c1-24-19-21-28(22-20-24)35(33,34)32-30(27-17-9-4-10-18-27)29(26-15-7-3-8-16-26)31-23-11-14-25-12-5-2-6-13-25;;/h2-10,12-13,15-22,29-31H,11,14,23H2,1H3;1H;/q-1;;+2/p-1/t29-,30-;;/m0../s1
InChI key: MDABGVLQRDDWLY-ARDORAJISA-M
form: __
Quality Level: 100
optical activity: __
reaction suitability: __
mp: __
storage temp.: 2-8°C
SMILES string: O=NN1CC=CCC1c2cccnc2
InChI: 1S/C10H11N3O/c14-12-13-7-2-1-5-10(13)9-4-3-6-11-8-9/h1-4,6,8,10H,5,7H2
InChI key: __
form: __
Quality Level: 100
optical activity: __
reaction suitability: __
mp: __
storage temp.: 2-8°C
SMILES string: O=NN1CCCCC1c2cccnc2
InChI: 1S/C10H13N3O/c14-12-13-7-2-1-5-10(13)9-4-3-6-11-8-9/h3-4,6,8,10H,1-2,5,7H2
InChI key: __
