692352

Magnesium bis(hexamethyldisilazide)

97%

Manufacturer: Sigma Aldrich

CAS Number: 857367-60-3

Synonym(S): Bis(hexamethyldisilazido)magnesium, Mg(HMDS)2

Select a Size

Pack Size SKU Availability Price
5 G 692352-5-G In Stock ₹ 16,529.78
25 G 692352-25-G In Stock ₹ 35,354.45

692352 - 5 G

₹ 16,529.78

In Stock

Quantity

1

Base Price: ₹ 16,529.78

GST (18%): ₹ 2,975.36

Total Price: ₹ 19,505.14

Quality Level

100

Assay

97%

form

solid

mp

121-124 °C

SMILES string

C[Si](C)(C)N([Mg]N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

InChI

1S/2C6H18NSi2.Mg/c2*1-8(2,3)7-9(4,5)6;/h2*1-6H3;/q2*-1;+2

InChI key

WYPTZCBYSQFOQS-UHFFFAOYSA-N

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Description

  • Application: Magnesium bis(hexamethyldisilazide) is an essential precursor in the synthesis of wide range of diketiminate ligand complexes for rac-lactide polymerization.[1][2][3] It can also be used in the synthesis of ItBu:Mg[N(SiMe3)2]2, where ItBu = (1,3-di-tert-butylimidazol-2-ylidene), a catalyst for the guanylation reaction of addition of amine to carbodiimide.[4]

SAFETY INFORMATION

Pictograms

GHS05

Signal Word

Danger

Hazard Statements

H314

Precautionary Statements

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Skin Corr. 1B

Supplementary Hazards

EUH014

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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solid

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SMILES string:
C[Si](C)(C)N([Mg]N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

InChI:
1S/2C6H18NSi2.Mg/c2*1-8(2,3)7-9(4,5)6;/h2*1-6H3;/q2*-1;+2

InChI key:
WYPTZCBYSQFOQS-UHFFFAOYSA-N

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SMILES string:
Brc1cnc2[nH]ccc2c1

InChI:
1S/C7H5BrN2/c8-6-3-5-1-2-9-7(5)10-4-6/h1-4H,(H,9,10)

InChI key:
LPTVWZSQAIDCEB-UHFFFAOYSA-N