731382

(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate

Manufacturer: Sigma Aldrich

CAS Number: 1361315-26-5

Synonym(S): Fe(R,R-PDP), Iron(II) (R,R-(2-({(R)-2-[(R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate, White-Chen catalyst, [Fe(R,R-PDP)(CH3CN)2](SbF6)2

Select a Size

Pack Size SKU Availability Price
500 MG 731382-500-MG In Stock ₹ 37,844.20

731382 - 500 MG

₹ 37,844.20

In Stock

Quantity

1

Base Price: ₹ 37,844.20

GST (18%): ₹ 6,811.956

Total Price: ₹ 44,656.156

form

powder

Quality Level

100

reaction suitability

core: ironreagent type: catalyst

greener alternative product characteristics

CatalysisLearn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

215-226 °C

greener alternative category

, Aligned

SMILES string

[Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4

InChI

1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1

InChI key

XUNWHBGEOCZDBX-QSKJABRXSA-B

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Description

  • General description: We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.
  • Application: Catalyst for greener ketone synthesis by selective C-H oxidation of methylenes.Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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form:
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CatalysisLearn more about the Principles of Green Chemistry.

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greener alternative category:
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SMILES string:
[Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4

InChI:
1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1

InChI key:
XUNWHBGEOCZDBX-QSKJABRXSA-B

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SMILES string:
Ic1ccc2ncccc2c1

InChI:
1S/C9H6IN/c10-8-3-4-9-7(6-8)2-1-5-11-9/h1-6H

InChI key:
WKTASELJZCIVBR-UHFFFAOYSA-N