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SDS
673293

Pentamethylcyclopentadienylbis(triphenylphosphine)ruthenium(II) chloride

Manufacturer: Sigma Aldrich

CAS Number: 92361-49-4

Synonym(S): Cp*RuCl(PPh3)2, Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II)

Select a Size

Pack Size SKU Availability Price
250 MG 673293-250-MG In Stock ₹ 15,462.30
1 G 673293-1-G In Stock ₹ 44,277.90

673293 - 250 MG

₹ 15,462.30

In Stock

Quantity

1

Base Price: ₹ 15,462.30

GST (18%): ₹ 2,783.214

Total Price: ₹ 18,245.514

form

solid

Quality Level

100

reaction suitability

core: rutheniumreagent type: catalystreaction type: click chemistry

mp

128 °C (D)

storage temp.

2-8°C

SMILES string

Cl[Ru].C[C]1[C](C)[C](C)[C](C)[C]1C.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7

InChI

1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;;;+1/p-1

InChI key

KLXKSZDVKAWYRT-UHFFFAOYSA-M

Other Options

Image Product Name Manufacturer Price Range
50-245-460
Strem, An Ascensus Company CAS# 92361-49-4. Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II), 99%. MFCD09038426. 250MG
Strem, An Ascensus Company ₹ 8,932.46

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Description

  • Application: Catalyst employed in the cycloaddtion of azides with acetylenes giving exclusively the 1,5-disubstitutedtriazoles in contrast to the 1,4-regiochemistry commonly observed with copper catalysis. Ruthenium catalysis also enables the use of internal acetylenes in these "click cycloaddtions".[1]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Compare Similar Items

Show Difference

Img

Sigma Aldrich

673293

--

form:
solid
Quality Level:
100
reaction suitability:
core: rutheniumreagent type: catalystreaction type: click chemistry
mp:
128 °C (D)
storage temp.:
2-8°C
SMILES string:
Cl[Ru].C[C]1[C](C)[C](C)[C](C)[C]1C.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
InChI:
1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;;;+1/p-1
InChI key:
KLXKSZDVKAWYRT-UHFFFAOYSA-M

Img

Sigma Aldrich

673307

--

form:
solid
Quality Level:
100
reaction suitability:
core: rutheniumreagent type: catalyst
mp:
__
storage temp.:
2-8°C
SMILES string:
[Ru+].CC#N.CC#N.CC#N.[CH]1[CH][CH][CH][CH]1.F[P-](F)(F)(F)(F)F
InChI:
1S/C5H5.3C2H3N.F6P.Ru/c1-2-4-5-3-1;3*1-2-3;1-7(2,3,4,5)6;/h1-5H;3*1H3;;/q;;;;-1;+1
InChI key:
HJQVFVSAQOQXRG-UHFFFAOYSA-N

Img

Sigma Aldrich

673331

97%...

form:
solid
Quality Level:
100
reaction suitability:
__
mp:
132-140 °C
storage temp.:
__
SMILES string:
CC(C)(C)c1cc(CN2CCOCC2)c(O)c(\C=N\[C@@H]3CCCC[C@H]3\N=C\c4cc(cc(CN5CCOCC5)c4O)C(C)(C)C)c1
InChI:
1S/C38H56N4O4/c1-37(2,3)31-19-27(35(43)29(21-31)25-41-11-15-45-16-12-41)23-39-33-9-7-8-10-34(33)40-24-28-20-32(38(4,5)6)22-30(36(28)44)26-42-13-17-46-18-14-42/h19-24,33-34,43-44H,7-18,25-26H2,1-6H3/b39-23+,40-24+/t33-,34-/m1/s1
InChI key:
ZSDPYCVORQDIHQ-DSANSEMASA-N

Img

Supelco

67334

Selectophore™, ≥99.9%...

form:
solid
Quality Level:
200
reaction suitability:
__
mp:
__
storage temp.:
__
SMILES string:
__
InChI:
__
InChI key:
__